Anions of 1,3,5-Benzenetricarboxylic and Heptanedioic Acids Serving as Bridges between Dimolybdenum(V) Metal-Metal Bonded Units: Preparation and Structural Characterization of Dinuclear and Tetranuclear Complexes
作者： Barbara Modec , Jurij V. Brenčič
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摘要: (PyH) 5 [MoOCl 4 (H 2 O)] 3 Cl and (PyH)[MoOBr ] reacted with the anions of 1,3,5-benzenetricarboxylic acid (btcH ) heptanedioic (hdaH to afford a series novel carboxylato complexes based on (Mo O + structural core: [Mo (μ -btcH )]Cl (1), Br )]Br (2), [(Mo Py -btcH) ].6Py (3), (PYH) 6 -[(Mo -hda)].2CH CN (4), 1 0 ((Mo -(μ -hda)](MoOCl ]Cl (5) (Py = pyridine, C H N; PyH pyridinium cation, NH ; btcH - (HOOC) COO (HOOC)C (COO) hda -OOC(CH -COO ). A pair isostructral compounds contains dinuclear X )] (X Cl, Br) in which ligand is bonded core via one carboxylate group syn-syn bidentate bridging manner. In 3, two ligands link cores into loop-like structure. Each coordinated groups, manner another monodentate The linkage subunits was also realized -hda)] , anion 5, where both groups bind bidentate-bridging cores. title were characterized by X-ray crystallography infrared spectroscopy.
sci-hub.se 参考文章(49)
S. J. Lippard, W. B. Tolman, R. Lynn Rardin, Monodentate carboxylate complexes and the carboxylate shift : implications for polymetalloprotein structure and function New Journal of Chemistry. ,vol. 15, pp. 417- 430 ,(1991)
F. Secheresse, B. Salignac, E. Cadot, A. Dolbecq, Chelating and / or templating role of oxalates with {M2S2O2}2+ building units M = Mo, W. Examples of [Mo2S2O2(C2O4)2(H2O)2]2-[M4S4O4(C2)4)5]6- M = Mo, W and [Mo8S8(OH)8(C2O4)]2- Bulletin of The Polish Academy of Sciences-chemistry. ,vol. 46, pp. 237- 271 ,(1998)
Graeme R. Hanson, Andrew A. Brunette, Angus C. McDonell, Keith S. Murray, Anthony G. Wedd, Electronic properties of thiolate compounds of oxomolybdenum(V) and their tungsten and selenium analogs. Effects of oxygen-17, molybdenum-98, and molybdenum-95 isotope substitution upon ESR spectra Journal of the American Chemical Society. ,vol. 103, pp. 1953- 1959 ,(1981) , 10.1021/JA00398A013
Zbyszek Otwinowski, Wladek Minor, Processing of X-ray diffraction data collected in oscillation mode Methods in Enzymology. ,vol. 276, pp. 307- 326 ,(1997) , 10.1016/S0076-6879(97)76066-X
Kazuo Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds ,(1978)
Myriam Riou-Cavellec, Catherine Albinet, Jean-Marc Grenèche, Gérard Férey, None, Study of the iron/trimesic acid system for the hydrothermal synthesis of hybrid materials Journal of Materials Chemistry. ,vol. 11, pp. 3166- 3171 ,(2001) , 10.1039/B104495H
Marina Cindrić, Višnja Vrdoljak, Biserka Prugovečki, Boris Kamenar, New dinuclear thiobenzoato complexes of molybdenum(V) containing Mo2O2S2 core. X-ray crystal structures of [Mo2O2S2(OSCC6H5)2(py)2] and [Mo2O2S2(OSCC6H5)2(γ-pic)2]·2H2O Polyhedron. ,vol. 17, pp. 3321- 3325 ,(1998) , 10.1016/S0277-5387(98)00111-9
Mirela Pascu, Francesc Lloret, Narcis Avarvari, Miguel Julve, Marius Andruh, Ferromagnetic Coupling through Spin Polarization in the Hexanuclear [MnII3CuII3] Complex Inorganic Chemistry. ,vol. 43, pp. 5189- 5191 ,(2004) , 10.1021/IC0493651
Bernadette Salignac, Sandra Riedel, Anne Dolbecq, Francis Sécheresse, Emmanuel Cadot, “Wheeling Templates” in Molecular Oxothiomolybdate Rings: Syntheses, Structures, and Dynamics Journal of the American Chemical Society. ,vol. 122, pp. 10381- 10389 ,(2000) , 10.1021/JA001878T
Barbara Modec, Jurij V. Brenčič, Eric M. Burkholder, Jon Zubieta, Novel molybdenum(V) squarato complexes based on the dinuclear metal–metal bonded unit: syntheses and structural characterization of dinuclear [Mo2O4(C4O4)(R-Py)4] and tetranuclear [Mo4O8(C4O4)4]4− Dalton Transactions. pp. 4618- 4625 ,(2003) , 10.1039/B311348E