Direct reductive amination and selective 1,2-reduction of α,β-unsaturated aldehydes and ketones by NaBH4 using H3PW12O40 as catalyst
作者： Akbar Heydari , Samad Khaksar , Jafar Akbari , Maryam Esfandyari , Mehrdad Pourayoubi
DOI: 10.1016/J.TETLET.2006.12.069
关键词:
摘要: Abstract A simple and convenient procedure for direct reductive amination of aldehydes ketones with sodium borohydride is described. The reaction has been carried out in methanol the presence a catalytic amount H 3 PW 12 O 40 (0.5 mol %). α,β-Unsaturated can be easily converted into corresponding allyl alcohols by (0.5 mol %)/NaBH 4 .
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