Nanoreactor Based on Macroporous Single Crystals of Metal-Organic Framework
作者： Shuhai Wang , Yanan Fan , Jun Teng , Yan-Zhong Fan , Ji-Jun Jiang
关键词:
摘要: A sacrificial template strategy is developed for the synthesis of yolk–shell Au@ZIF-8 nanoreactor. The nanoreactor possesses single-crystalline metal-organic framework (MOF) shell with intrinsic monodisperse micropores and introduced macropores. In each macropores, one Au NP encapsulated to form a unit. quantity reactor units in MOF can be readily regulated. Such structure features facilitate size selectivity reactants, accessibility nanoparticles mass transfer reactants products. As result, delivers excellent selectivity, enhanced conversion, good cycling stability when used catalyze aerobic oxidation alcohols different molecular size.
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