On the structure of defect centers in γ-irradiated alkali silicate glasses
作者： R. Cases , D.L. Griscom
DOI: 10.1016/0168-583X(84)90116-2
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摘要: An EPR study after room temperature γ-irradiation on potassium silicate glasses of two chemical compositions and different 17O 29Si isotopic enrichments has been carried out. Isochronal anneal experiments 17O-enriched samples have confirmed the model for trapped-hole center HC1 as comprising a trapped hole pure 2pπ orbital single nonbridging oxygen. Besides well known HC2 spectra, new resonances isolated identified due to three types oxygen-related defects (interstitial O2− ions; bonded glass network; interstitial ozonide ions O3−). Using 29Si-enriched samp simulations 370 G doublet demonstrated arise from an E'-like defect which tentative is given. The formation all these by irradiation depends composition glass.
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sci-hub.se 参考文章(22)
C. Austen Angell, Joe Wong, Glass : structure by spectroscopy M. Dekker. ,(1976)
G. Kordas, B. Camara, H.J. Oel, Electron spin resonance studies of radiation damage in silicate glasses Journal of Non-crystalline Solids. ,vol. 50, pp. 79- 95 ,(1982) , 10.1016/0022-3093(82)90202-2
J. W. H. Schreurs, Study of Some Trapped Hole Centers in X‐Irradiated Alkali Silicate Glasses The Journal of Chemical Physics. ,vol. 47, pp. 818- 830 ,(1967) , 10.1063/1.1711956
Janice M. DeLisle, R. M. Golding, ESR Study of X‐Irradiated Sodium Thiosulfate Single Crystals The Journal of Chemical Physics. ,vol. 43, pp. 3298- 3303 ,(1965) , 10.1063/1.1726391
D.L. Griscom, Electron spin resonance in glasses Journal of Non-Crystalline Solids. ,vol. 40, pp. 211- 272 ,(1980) , 10.1016/0022-3093(80)90105-2
D. L. Griscom, ESR Studies of an Intrinsic Trapped‐Electron Center in X‐Irradiated Alkali Borate Glasses The Journal of Chemical Physics. ,vol. 55, pp. 1113- 1122 ,(1971) , 10.1063/1.1676194
David L. Griscom, E′center in glassy SiO2: Microwave saturation properties and confirmation of the primarySi29hyperfine structure Physical Review B. ,vol. 20, pp. 1823- 1834 ,(1979) , 10.1103/PHYSREVB.20.1823
E. J. Friebele, D. L. Griscom, M. Stapelbroek, R. A. Weeks, Fundamental Defect Centers in Glass: The Peroxy Radical in Irradiated, High-Purity, Fused Silica Physical Review Letters. ,vol. 42, pp. 1346- 1349 ,(1979) , 10.1103/PHYSREVLETT.42.1346
D. M. Yudin, N. G. Cherenda, A. V. Shendrik, Hyperfine interactions in high-silicate and quartz glasses Physica Status Solidi B-basic Solid State Physics. ,vol. 69, pp. 687- 698 ,(1975) , 10.1002/PSSB.2220690245
D.L. Griscom, Defects in amorphous insulators Journal of Non-crystalline Solids. ,vol. 31, pp. 241- 266 ,(1978) , 10.1016/0022-3093(78)90107-2