Investigation of Morphology, Crystallinity, Thermal stability, Piezoelectricity and Conductivity of PVDF nanocomposites reinforced with Epoxy Functionalized MWCNTs
作者： Ayesha Kausar , Irfan Ahmed , Hameed Ullah , Saddiqa Begum , Yiqiang Zhan
DOI: 10.1016/J.COMPSCITECH.2021.108841
关键词:
摘要: Abstract In order to improve the dispersion state of multi-walled carbon nanotubes (MWCNTs) and get a synergistic effect when incorporated in polyvinylidene flouride (PVDF) matrix, were oxidized then grafted with di-glycidyl ether bisphenol-A (DGEBA) by linker moiety, hexamethylene diamine (HMD). Modified MWCNTs (HD-MWCNTs various concentrations 1.0 wt.% 10 fluoride matrix for fabrication polymeric nanocomposites (PVDF/HD-MWCNTs). Compared pristine (P-MWCNTs), structural thermal analysis both modified showed well crystalline structure uniform tubular morphology as improved was achieved their PVDF. Enhanced is attributed strong interfacial interaction polymer chains Therefore, PVDF/HD-MWCNTs melting temperature (Tm) crystallization (Tc) have revealed distribution enhancement heterogeneous nucleating leading formation β-phase which complete agreement SEM, FTIR, XRD, TGA d33 value. Piezoelectric electrical conductivity values measured observed rise increase concentration HD-MWCNTs up 5 where percolation threshold (fc) attained. nanocomposite highest 1.13 x 10-3 Scm-1 at filler loading 5.0 successfully achieved. These simultaneous improvement properties anticipate that can be useful variety energy applications.
sci-hub.st 参考文章(49)
Carsten Schilde, Mario Schlömann, Achim Overbeck, Stefan Linke, Arno Kwade, Thermal, mechanical and electrical properties of highly loaded CNT-epoxy composites – A model for the electric conductivity Composites Science and Technology. ,vol. 117, pp. 183- 190 ,(2015) , 10.1016/J.COMPSCITECH.2015.06.013
Yusong Zhu, Shiying Xiao, Yi Shi, Yaqiong Yang, Yuyang Hou, Yuping Wu, A Composite Gel Polymer Electrolyte with High Performance Based on Poly(Vinylidene Fluoride) and Polyborate for Lithium Ion Batteries Advanced Energy Materials. ,vol. 4, pp. 1300647- ,(2014) , 10.1002/AENM.201300647
Ami Eitan, Kuiyang Jiang, Doug Dukes, Rodney Andrews, Linda S. Schadler, Surface modification of multiwalled carbon nanotubes: Toward the tailoring of the interface in polymer composites Chemistry of Materials. ,vol. 15, pp. 3198- 3201 ,(2003) , 10.1021/CM020975D
Ali Bahader, Haoguan Gui, Yu Li, Pei Xu, Yunsheng Ding, Crystallization kinetics of PVDF filled with multi wall carbon nanotubes modified by amphiphilic ionic liquid Macromolecular Research. ,vol. 23, pp. 273- 283 ,(2015) , 10.1007/S13233-015-3039-8
Mengyuan Li, Harry J. Wondergem, Mark-Jan Spijkman, Kamal Asadi, Ilias Katsouras, Paul W. M. Blom, Dago M. de Leeuw, Revisiting the delta-phase of poly(vinylidene fluoride) for solution-processed ferroelectric thin films Nature Materials. ,vol. 12, pp. 433- 438 ,(2013) , 10.1038/NMAT3577
Alvaro Carrillo, Jeffrey A. Swartz, Jason M. Gamba, Ravi S. Kane, Nirupama Chakrapani, Bingqing Wei, Pulickel M. Ajayan, NONCOVALENT FUNCTIONALIZATION OF GRAPHITE AND CARBON NANOTUBES WITH POLYMER MULTILAYERS AND GOLD NANOPARTICLES Nano Letters. ,vol. 3, pp. 1437- 1440 ,(2003) , 10.1021/NL034376X
Il-Hwan Kim, Doo Hyun Baik, Young Gyu Jeong, Structures, electrical, and dielectric properties of PVDF-based nanocomposite films reinforced with neat multi-walled carbon nanotube Macromolecular Research. ,vol. 20, pp. 920- 927 ,(2012) , 10.1007/S13233-012-0064-8
Yi Lin, Apparao M. Rao, Bindu Sadanadan, Edward A. Kenik, Ya-Ping Sun, Functionalizing multiple-walled carbon nanotubes with aminopolymers Journal of Physical Chemistry B. ,vol. 106, pp. 1294- 1298 ,(2002) , 10.1021/JP013501V
Nicole Levi, Richard Czerw, Shuya Xing, Preethi Iyer, David L. Carroll, Properties of Polyvinylidene Difluoride−Carbon Nanotube Blends Nano Letters. ,vol. 4, pp. 1267- 1271 ,(2004) , 10.1021/NL0494203
Stefanie A. Sydlik, Jae-Hwang Lee, Joseph J. Walish, Edwin L. Thomas, Timothy M. Swager, Epoxy functionalized multi-walled carbon nanotubes for improved adhesives Carbon. ,vol. 59, pp. 109- 120 ,(2013) , 10.1016/J.CARBON.2013.02.061