Monte-carlo simulation of gas chromatographic separation for the prediction of retention times and peak half widths
作者： M. Wernekenschnieder , P. Zinn
DOI: 10.1007/BF02260768
关键词:
摘要: A new method for prediction of gas chromatographic retention times and peak half widths is based on the renewal theory. The only requirements are heats vaporization compounds to be separated one calibration measurement. With this data, can predicted isothermal as well temperature-programmed chromatography. For separation non-polar substances stationary phases error approx. 1–2%. First simulations polar molecules indicate that also applicable in these cases but some extension will required.
springer.com
sci-hub.se 参考文章(23)
J. R. Partington, An advanced treatise on physical chemistry ,(1949)
A. J. P. Martin, R. L. M. Synge, A new form of chromatogram employing two liquid phases Biochemical Journal. ,vol. 35, pp. 1358- 1368 ,(1941) , 10.1042/BJ0351358
E. Marengo, C. Baiocchi, M. C. Gennaro, P. Bertolo, Prediction of HPLC retention times in gradient elution from isocratic data application to a set of non-homologous compounds and different stationary phases Chromatographia. ,vol. 27, pp. 19- 23 ,(1989) , 10.1007/BF02290398
Jeng Chyh. Chen, Stephen G. Weber, Theoretical and experimental determination of band broadening in liquid chromatography Analytical Chemistry. ,vol. 55, pp. 127- 134 ,(1983) , 10.1021/AC00252A033
Sterling A. Tomellini, Shih Hsien. Hsu, Richard A. Hartwick, Prediction of retention for coupled column gradient elution high-performance liquid chromatography Analytical Chemistry. ,vol. 58, pp. 904- 906 ,(1986) , 10.1021/AC00295A055
M. A. Quarry, R. L. Grob, L. R. Snyder, Prediction of precise isocratic retention data from two or more gradient elution runs. Analysis of some associated errors Analytical Chemistry. ,vol. 58, pp. 907- 917 ,(1986) , 10.1021/AC00295A056
Mohamed Noor. Hasan, Peter C. Jurs, Computer-assisted prediction of liquid chromatographic retention indexes of polycyclic aromatic hydrocarbons Analytical Chemistry. ,vol. 55, pp. 263- 269 ,(1983) , 10.1021/AC00253A020
K. Jinno, M. Yamagami, M. Kuwajima, Retention prediction and computer-assisted optimization for the separation of PTH-amino acids in isocratic reversed-phase liquid chromatography Chromatographia. ,vol. 25, pp. 974- 982 ,(1988) , 10.1007/BF02259415
Lutgarde. Buydens, Desire L. Massart, Paul. Geerlings, Prediction of gas chromatographic retention indexes with topological, physicochemical, and quantum chemical parameters Analytical Chemistry. ,vol. 55, pp. 738- 744 ,(1983) , 10.1021/AC00255A034
R. H. Rohrbaugh, P. C. Jurs, Prediction of gas chromatographic retention indexes of polycyclic aromation compounds and nitrated polycyclic aromatic compounds Analytical Chemistry. ,vol. 58, pp. 1210- 1212 ,(1986) , 10.1021/AC00297A052