A Strong Contradiction in the Conventional Non-relativistic Theory of the Ground State Helium Atom and Helium-like Ions

作者: Viktor D. Ignatiev

DOI:

关键词:

摘要: In the conventional theory of ground state heliu m ato m, any solution two-electron Schrodinger equation is wrong! That caused by a strong imbalance proportions attraction versus repulsion operators' acting on wave function, in initial differential and its integral algebraic form. equation, operators act radial part function independently fro one another obeying true proportion: per electron. But resulting turns out to satisfy wrong two energies energy The underlying contradiction un-coincidence additivity rules operators: whereas electrons may be summed corresponding referred different not. Consequences this principal are d iscussed.

参考文章(20)
Gordon W. F. Drake, Atomic, molecular, & optical physics handbook American Institute of Physics. ,(1996)
H. A. Bethe, E. E. Salpeter, Quantum Mechanics of One- and Two-Electron Atoms Quantum Mechanics of One- and Two-Electron Atoms. ,vol. 7, pp. 88- 436 ,(1957) , 10.1007/978-3-642-45869-9_2
Hiroyuki Nakashima, Hiroshi Nakatsuji, Solving the Schrödinger equation for helium atom and its isoelectronic ions with the free iterative complement interaction "ICI… method Journal of Chemical Physics. ,vol. 127, pp. 224104- 224104 ,(2007) , 10.1063/1.2801981
Vladimir Korobov, Alexander Yelkhovsky, Ionization Potential of the Helium Atom Physical Review Letters. ,vol. 87, pp. 193003- ,(2001) , 10.1103/PHYSREVLETT.87.193003
Egil A. Hylleraas, Neue Berechnung der Energie des Heliums im Grundzustande, sowie des tiefsten Terms von Ortho-Helium European Physical Journal. ,vol. 54, pp. 347- 366 ,(1929) , 10.1007/BF01375457
James S. Sims, Stanley A. Hagstrom, High‐precision Hy–CI variational calculations for the ground state of neutral helium and helium‐like ions International Journal of Quantum Chemistry. ,vol. 90, pp. 1600- 1609 ,(2002) , 10.1002/QUA.10344
E P Ivanova, U I Safronova, Perturbation theory in calculations of atomic energy levels Journal of Physics B. ,vol. 8, pp. 1591- 1602 ,(1975) , 10.1088/0022-3700/8/10/011
C. L. Pekeris, Ground State of Two-Electron Atoms Physical Review. ,vol. 112, pp. 1649- 1658 ,(1958) , 10.1103/PHYSREV.112.1649
Georg Wolfgang Kellner, Die Ionisierungsspannung des Heliums nach der Schrödingerschen Theorie European Physical Journal. ,vol. 44, pp. 91- 109 ,(1927) , 10.1007/BF01391720
Alexei M. Frolov, TWO-STAGE STRATEGY FOR HIGH-PRECISION VARIATIONAL CALCULATIONS Physical Review A. ,vol. 57, pp. 2436- 2439 ,(1998) , 10.1103/PHYSREVA.57.2436