Modelling complex organic molecules in dense regions: Eley–Rideal and complex induced reaction

作者: M. Ruaud , J. C. Loison , K. M. Hickson , P. Gratier , F. Hersant

DOI: 10.1093/MNRAS/STU2709

关键词:

摘要: Recent observations have revealed the existence of Complex Organic Molecules (COMs) in cold dense cores and prestellar cores. The presence these molecules such conditions is not well understood remains a matter debate since previously proposed "warm- up" scenario cannot explain observations. In this article, we study effect Eley- Rideal complex induced reaction mechanisms gas-phase carbon atoms with main ice components dust grains on formation COMs regions. Based recent experiments use low value for chemical desorption efficiency (which was invoked to observed COM abundances). We show that our introduced are efficient enough produce large amount organic at temperatures as 10K.

参考文章(108)
K. M. Hickson, S. J. Klippenstein, J. C. Loison, W. D. Geppert, A. Bergeat, I. W. M. Smith, D. Talbi, Valentine Wakelam, Review of important reactions for the nitrogen chemistry in the interstellar medium arXiv: Astrophysics of Galaxies. ,(2013)
A. G. G. M. Tielens, S. B. Charnley, Circumstellar and Interstellar Synthesis of Organic Molecules Planetary and Interstellar Processes Relevant to the Origins of Life. ,vol. 27, pp. 23- 51 ,(1997) , 10.1007/978-94-015-8907-9_3
Ewine F. van Dishoeck, Geert-Jan Kroes, Carina Arasa, Marc C. van Hemert, Molecular Dynamics Simulations of CO2 Formation in Interstellar Ices arXiv: Chemical Physics. ,(2013) , 10.1021/JP400065V
R. T. Garrod, T. Pauly, ON THE FORMATION OF CO2AND OTHER INTERSTELLAR ICES The Astrophysical Journal. ,vol. 735, pp. 15- ,(2011) , 10.1088/0004-637X/735/1/15
Ameya V. Joshi, Hai Wang, Master equation modeling of wide range temperature and pressure dependence of CO + OH → products International Journal of Chemical Kinetics. ,vol. 38, pp. 57- 73 ,(2006) , 10.1002/KIN.20137
J. V. Michael, D. F. Nava, W. A. Payne, L. J. Stief, Absolute rate constants for the reaction of atomic hydrogen with ketene from 298 to 500 K Journal of Chemical Physics. ,vol. 70, pp. 5222- 5227 ,(1979) , 10.1063/1.437314
R. T. Garrod, E. Herbst, Formation of methyl formate and other organic species in the warm-up phase of hot molecular cores Astronomy and Astrophysics. ,vol. 457, pp. 927- 936 ,(2006) , 10.1051/0004-6361:20065560
Richard A. Yetter, Herschel Rabitz, Frederick L. Dryer, Robert G. Maki, R. Bruce Klemm, Evaluation of the rate constant for the reaction OH+H2CO: Application of modeling and sensitivity analysis techniques for determination of the product branching ratio Journal of Chemical Physics. ,vol. 91, pp. 4088- 4097 ,(1989) , 10.1063/1.456838