Identification and Estimation of (+)-Abscisin II (‘Dormin’) in Plant Extracts by Spectropolarimetry
作者： J. W. CORNFORTH , B. V. MILBORROW , G. RYBACK
DOI: 10.1038/210627A0
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摘要: ABSCISIN II is a recently discovered1,2 plant hormone which appears to inhibit the action of auxins, gibberellins and kinins3. Its structure4 (I) contains one centre asymmetry, comparison its properties with those synthetic5 (±)-abscisin suggested that natural substance single enantiomorph. We have now measured optical rotatory dispersion abscisin from sycamore leaves2, find this source dextro-rotatory exhibits very intense positive Cotton effect extrema at 287 mµ ([α] + 24,000°) 245 − 69,000°):
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W. Ruhland, Handbuch der Pflanzenphysiologie Springer-Verlag. ,(1955)
C. F. EAGLES, P. F. WAREING, Dormancy Regulators in Woody Plants: Experimental Induction of Dormancy in Betula pubescens Nature. ,vol. 199, pp. 874- 875 ,(1963) , 10.1038/199874A0
K. Ohkuma, J. L. Lyon, F. T. Addicott, O. E. Smith, Abscisin II, an Abscission-Accelerating Substance from Young Cotton Fruit Science. ,vol. 142, pp. 1592- 1593 ,(1963) , 10.1126/SCIENCE.142.3599.1592
H. Schütte, Handbuch der Pflanzenphysiologie Band VIII Der Stickstoffumsatz Von W. Ruhland. Springer‐Verlag, Berlin‐Göttingen‐Heidelberg 1958. 1146 S., zahlr. Abb. u. Tab. Preis Glw. DM 286,—. Zeitschrift für Chemie. ,vol. 1, pp. 192- 192 ,(2010) , 10.1002/ZFCH.19610010615
J. W. CORNFORTH, B. V. MILBORROW, G. RYBACK, P. F. WAREING, Chemistry and Physiology of ‘Dormins’ In Sycamore: Identity of Sycamore ‘Dormin’ with Abscisin II Nature. ,vol. 205, pp. 1269- 1270 ,(1965) , 10.1038/2051269B0
J. W. CORNFORTH, B. V. MILBORROW, G. RYBACK, Synthesis of (±)-Abscisin II Nature. ,vol. 206, pp. 715- 715 ,(1965) , 10.1038/206715A0
K. Ohkuma, F.T. Addicott, O.E. Smith, W.E. Thiessen, The structure of abscisin II Tetrahedron Letters. ,vol. 6, pp. 2529- 2535 ,(1965) , 10.1016/S0040-4039(01)84019-3
G. A. D. Jackson, J. B. Blundell, Germination in Rosa Journal of Horticultural Science. ,vol. 38, pp. 310- 320 ,(2015) , 10.1080/00221589.1963.11514082