Upgrading of Bio-oil over Aluminum Silicate in Supercritical Ethanol
作者： Jun Peng , Ping Chen , Hui Lou , Xiaoming Zheng
DOI: 10.1021/EF8001789
关键词:
摘要: The crude bio-oil from fast pyrolysis of rice husk was upgraded in supercritical ethanol using aluminum silicate as a catalyst. results showed that the upgrading process performed effectively and components were optimized greatly. Acidic facilitates esterification to convert most acids contained into various kinds esters. amount phenols exist extensively decreased during process. Aldehydes, such furfural vanillin, which are typically present bio-oil, removed not detected bio-oil. residue distillated evidently compared density kinematical viscosity pH value heating increased o...
acs.org
cheric.org参考文章(22)
J GADHE, R GUPTA, Hydrogen production by methanol reforming in supercritical water: Catalysis by in-situ-generated copper nanoparticles International Journal of Hydrogen Energy. ,vol. 32, pp. 2374- 2381 ,(2007) , 10.1016/J.IJHYDENE.2006.10.050
S Vitolo, B Bresci, M Seggiani, M.G Gallo, Catalytic upgrading of pyrolytic oils over HZSM-5 zeolite: behaviour of the catalyst when used in repeated upgrading–regenerating cycles Fuel. ,vol. 80, pp. 17- 26 ,(2001) , 10.1016/S0016-2361(00)00063-6
Douglas C. Elliott, Historical Developments in Hydroprocessing Bio-oils Energy & Fuels. ,vol. 21, pp. 1792- 1815 ,(2007) , 10.1021/EF070044U
N HIYOSHI, C RODE, O SATO, H TETSUKA, M SHIRAI, Stereoselective hydrogenation of tert-butylphenols over charcoal-supported rhodium catalyst in supercritical carbon dioxide solvent Journal of Catalysis. ,vol. 252, pp. 57- 68 ,(2007) , 10.1016/J.JCAT.2007.08.011
Qi Zhang, Jie Chang, Wang, Ying Xu, Upgrading Bio-oil over Different Solid Catalysts Energy & Fuels. ,vol. 20, pp. 2717- 2720 ,(2006) , 10.1021/EF060224O
Aristides C. Basagiannis, Xenophon E. Verykios, Steam reforming of the aqueous fraction of bio-oil over structured Ru/MgO/Al2O3 catalysts Catalysis Today. ,vol. 127, pp. 256- 264 ,(2007) , 10.1016/J.CATTOD.2007.03.025
Cyrille Rioche, Shrikant Kulkarni, Frederic C. Meunier, John P. Breen, Robbie Burch, Steam reforming of model compounds and fast pyrolysis bio-oil on supported noble metal catalysts Applied Catalysis B-environmental. ,vol. 61, pp. 130- 139 ,(2005) , 10.1016/J.APCATB.2005.04.015
Philip G. Jessop, Takao Ikariya, Ryoji Noyori, Homogeneous Catalysis in Supercritical Fluids. Chemical Reviews. ,vol. 99, pp. 475- 494 ,(1999) , 10.1021/CR970037A
Swapan K. Ghosh, Shigeru Deguchi, Sada-atsu Mukai, Kaoru Tsujii, Supercritical ethanol--a fascinating dispersion medium for silica nanoparticles. Journal of Physical Chemistry B. ,vol. 111, pp. 8169- 8174 ,(2007) , 10.1021/JP071999G
J PENNINGER, M REP, Reforming of aqueous wood pyrolysis condensate in supercritical water International Journal of Hydrogen Energy. ,vol. 31, pp. 1597- 1606 ,(2006) , 10.1016/J.IJHYDENE.2006.06.027