Generation and gas-phase reactivity of CoGa+
作者： Christian Kronseder , Thomas Schindler , Christian Berg , Roland Fischer , Gereon Niedner-Schatteburg
DOI: 10.1016/0022-328X(94)84029-6
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摘要: Abstract Electron impact ionization and subsequent fragmentation of volatile but stable organometallic precursor compounds is used to release naked CoGa + ions transfer into analyse by a high resolution Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometer. Gas-phase bimolecular reactions with methanol, among others, yield two distinct isomers (GaCH 3 OH) significant internal excitation. Ab initio calculations using density functional approach for complement the experimental findings.
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sci-hub.se 参考文章(47)
Roland A. Fischer, Thomas Priermeier, Wolfgang Scherer, Organo Group 13 metal complexes of d-block elements Journal of Organometallic Chemistry. ,vol. 459, pp. 65- 71 ,(1993) , 10.1016/0022-328X(93)86056-N
M. F. Cai, S. J. Tsay, T. P. Dzugan, K. Pak, V. E. Bondybey, Laser vaporization of alloys: fluorescence and electronic structure of aluminum-copper (AlCu) The Journal of Physical Chemistry. ,vol. 94, pp. 1313- 1316 ,(1990) , 10.1021/J100367A022
PA M VAN KOPPEN, J Brodbelt-Lustig, MT Bowers, DV Dearden, JL Beauchamp, ER Fisher, None, Transition Metal Ion Mediated C-H and C-C Bond Activation of Alkanes: Dynamical Coupling between Entrance and Exit Channel Transition States Journal of the American Chemical Society. ,vol. 113, pp. 2359- 2369 ,(1991) , 10.1021/JA00007A003
Ofer Blum, Detlef Stöckigt, Detlef Schröder, Helmut Schwarz, OH Bond Activation in the Gas Phase: The Reactions of Water and Methanol with[FeCH3]+ Angewandte Chemie International Edition in English. ,vol. 31, pp. 603- 604 ,(1992) , 10.1002/ANIE.199206031
Alan G. Marshall, D. Christopher Roe, Theory of Fourier transform ion cyclotron resonance mass spectroscopy: Response to frequency‐sweep excitation Journal of Chemical Physics. ,vol. 73, pp. 1581- 1590 ,(1980) , 10.1063/1.440338
D. J. Patmore, W. A. G. Graham, Organometallic Compounds with Metal-Metal Bonds. III. Tetracarbonylcobalt Derivatives of Gallium, Indium, and Thallium Inorganic Chemistry. ,vol. 5, pp. 1586- 1590 ,(1966) , 10.1021/IC50043A026
Melvin B. Comisarow, Alan G. Marshall, Theory of Fourier transform ion cyclotron resonance mass spectroscopy. I. Fundamental equations and low‐pressure line shape The Journal of Chemical Physics. ,vol. 64, pp. 110- 119 ,(1976) , 10.1063/1.431959
Melvin B. Comisarow, Comprehensive Theory for Ion Cyclotron Resonance Power Absorption: Application to Line Shapes for Reactive and Nonreactive Ions The Journal of Chemical Physics. ,vol. 55, pp. 205- 217 ,(1971) , 10.1063/1.1675510
J. Andzelm, E. Wimmer, Density functional Gaussian‐type‐orbital approach to molecular geometries, vibrations, and reaction energies Journal of Chemical Physics. ,vol. 96, pp. 1280- 1303 ,(1992) , 10.1063/1.462165
D. B. Jacobson, B. S. Freiser, Transition-metal cluster ions in the gas phase: oxide chemistry of dimeric and trimeric clusters containing iron and cobalt Journal of the American Chemical Society. ,vol. 108, pp. 27- 30 ,(1986) , 10.1021/JA00261A006