Enantioselective synthesis of homoallylic alcohols using (E)-but-2-enyl-trichlorosilane and chiral diamines
作者： Richard M. Angell , Anthony G. M. Barrett , D. Christopher Braddock , Steven Swallow , Benjamin D. Vickery
DOI: 10.1039/A701244F
关键词:
摘要: Condensation of aromatic aldehydes and (E)-but-2-enyl- trichlorosilane in the presence of (S)-(+)-4-(2-methylpropyl)-2-(2-pyridinyl)-2-oxazoline gives the corresponding homoallylic alcohols excellent anti-diastereoselectivity (>99%) good enantioselectivity (36–74%).
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