Organoselenium Chemistry in Stereoselective Reactions

作者: Thomas Wirth

DOI: 10.1002/1521-3773(20001103)39:21<3740::AID-ANIE3740>3.0.CO;2-N

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摘要: Selenium-based methods have developed rapidly over the past few years asnd organoselenium chemistry has become a very useful tool in hands of synthetic chemists. The different reactivity selenium-containing compounds contrast to sulfur analogues led versatile and new organic chemistry. Various functionalities can be selectively introduced into complex molecules under mild reaction conditions. In this review, principles are traced back their origins highlighted with respect stereoselective synthesis. unique properties selenium allow development highly selective transformations, which employed subsequently routes for synthesis chiral building blocks natural product

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