Effects of surface overpotential at the La1−xSrxCo1−yFeyO3-yttria stabilized zirconia interface in a model solid oxide fuel cell cathode

作者: S LIU , J SUO , J XIAO

DOI: 10.1016/J.IJHYDENE.2008.08.008

关键词:

摘要: The cathode–electrolyte interface microstructure and surface overpotential are important factors to decide the oxygen reduction rate. Thus, the effects of the surface overpotential and temperature at the strontium-and iron-doped lanthanum cobaltite (LSCF)/gadolinia-doped ceria (GDC) electrode interface on yitria-stabilized zirconia (YSZ) have been analyzed by AC impedance. At low anodic overpotential near the equilibrium, the impedance diagram is characterized by a resistance with approximately a constant value of 0.078 Ωcm2 at 1073K …

参考文章(13)
N.Q. Minh, T. Takahashi, Science and Technology of Ceramic Fuel Cells ,(2011)
K. Sasaki, J.‐P. Wurth, R. Gschwend, M. Gödickemeier, L. J. Gauckler, Microstructure‐Property Relations of Solid Oxide Fuel Cell Cathodes and Current Collectors Cathodic Polarization and Ohmic Resistance Journal of The Electrochemical Society. ,vol. 143, pp. 530- 543 ,(1996) , 10.1149/1.1836476
M DERIDDER, A VERVOORT, R VANWELZENIS, H BRONGERSMA, The limiting factor for oxygen exchange at the surface of fuel cell electrolytes Solid State Ionics. ,vol. 156, pp. 255- 262 ,(2003) , 10.1016/S0167-2738(02)00754-3
Shiming Liu, Xiaoliang Qian, Jianzhong Xiao, Synthesis and characterization of La0.8Sr0.2Co0.5Fe0.5O3±δ nanopowders by microwave assisted sol–gel route Journal of Sol-Gel Science and Technology. ,vol. 44, pp. 187- 193 ,(2007) , 10.1007/S10971-007-1628-5
Mette Juhl, Søren Primdahl, Carrie Manon, Mogens Mogensen, Performance/structure correlation for composite SOFC cathodes Journal of Power Sources. ,vol. 61, pp. 173- 181 ,(1996) , 10.1016/S0378-7753(96)02361-0
M.J.L. Østergård, C. Clausen, C. Bagger, M. Mogensen, Manganite-zirconia composite cathodes for SOFC: Influence of structure and composition Electrochimica Acta. ,vol. 40, pp. 1971- 1981 ,(1995) , 10.1016/0013-4686(94)00332-U
E. Siebert, A. Hammouche, M. Kleitz, Impedance spectroscopy analysis of La1 − xSritxMnO3-yttria-stabilized zirconia electrode kinetics Electrochimica Acta. ,vol. 40, pp. 1741- 1753 ,(1995) , 10.1016/0013-4686(94)00361-4
James R Wilson, Worawarit Kobsiriphat, Roberto Mendoza, Hsun-Yi Chen, Jon M Hiller, Dean J Miller, Katsuyo Thornton, Peter W Voorhees, Stuart B Adler, Scott A Barnett, None, Three-dimensional reconstruction of a solid-oxide fuel-cell anode Nature Materials. ,vol. 5, pp. 541- 544 ,(2006) , 10.1038/NMAT1668
V. Dusastre, J.A. Kilner, Optimisation of composite cathodes for intermediate temperature SOFC applications Solid State Ionics. ,vol. 126, pp. 163- 174 ,(1999) , 10.1016/S0167-2738(99)00108-3
Ji Haeng Yu, Gun Woo Park, Shiwoo Lee, Sang Kuk Woo, Microstructural effects on the electrical and mechanical properties of Ni-YSZ cermet for SOFC anode Journal of Power Sources. ,vol. 163, pp. 926- 932 ,(2007) , 10.1016/J.JPOWSOUR.2006.10.017