Electron Spin Resonance on polyurethanes – Vapor grown carbon nanofiber composites

作者: Mircea Chipara , Richard A. Vaia , Ali Nasar

DOI: 10.1016/J.VACUUM.2014.02.018

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摘要: Abstract Electron Spin Resonance investigations on polyurethane – vapor grown carbon nanofiber composites are reported. The research focuses the free radicals generated during processing step and ESR spectrum of conducting electrons delocalized over nanofiber. deactivation due to their interaction with residing was analyzed related enhanced stability these composites. dependence resonance line parameters concentration nanofiller is studied in detail. Experimental data indicates that electrical conductivity uncoupled domains suggests dominated by polarons. percolation also reflected data. interactions between electronic spins, as revealed width nanofibers discussed

参考文章(25)
Shuzhong Guo, Chao Zhang, Weizhi Wang, Tianxi Liu, Wuiwui Chauhari Tjiu, Chaobin He, Wei-De Zhang, None, Preparation and Characterization of Polyurethane/Multiwalled Carbon Nanotube Composites Polymers & Polymer Composites. ,vol. 16, pp. 501- 507 ,(2008) , 10.1177/096739110801600803
Kresten L.C. Nielsen, David J.T. Hill, Kent A. Watson, John W. Connell, Shigetoshi Ikeda, Hisaaki Kudo, Andrew K. Whittaker, The radiation degradation of a nanotube-polyimide nanocomposite Polymer Degradation and Stability. ,vol. 93, pp. 169- 175 ,(2008) , 10.1016/J.POLYMDEGRADSTAB.2007.10.010
Satoshi Ishii, Nobuyuki Aoki, Koichirou Miyamoto, Nobuko Oguri, Kazunaga Horiuchi, Yuichi Ochiai, CESR in multi walled carbon nanotubes Physica E-low-dimensional Systems & Nanostructures. ,vol. 17, pp. 386- 388 ,(2003) , 10.1016/S1386-9477(02)00889-5
P.S. Rama Sreekanth, N. Naresh Kumar, S. Kanagaraj, Improving post irradiation stability of high density polyethylene by multi walled carbon nanotubes Composites Science and Technology. ,vol. 72, pp. 390- 396 ,(2012) , 10.1016/J.COMPSCITECH.2011.11.031
Mircea Chipara, Jeffrey M. Zaleski, David Hui, Chunsheng Du, Ning Pan, Electron Spin Resonance on Carbon Nanotubes-Polymer Composites Journal of Polymer Science Part B. ,vol. 43, pp. 3406- 3412 ,(2005) , 10.1002/POLB.20647
Hilmar Koerner, Weidong Liu, Max Alexander, Peter Mirau, Heather Dowty, Richard A. Vaia, Deformation–morphology correlations in electrically conductive carbon nanotube—thermoplastic polyurethane nanocomposites Polymer. ,vol. 46, pp. 4405- 4420 ,(2005) , 10.1016/J.POLYMER.2005.02.025
Jaewu Choi, Mircea Chipara, B Xu, C.S Yang, B Doudin, P.A Dowben, Comparison of the π-conjugated ring orientations in polyaniline and polypyrrole Chemical Physics Letters. ,vol. 343, pp. 193- 200 ,(2001) , 10.1016/S0009-2614(01)00469-9
Wei Chen, Xiaoming Tao, Yuyang Liu, Carbon nanotube-reinforced polyurethane composite fibers Composites Science and Technology. ,vol. 66, pp. 3029- 3034 ,(2006) , 10.1016/J.COMPSCITECH.2006.01.024
Yuichi Ochiai, Ryousuke Enomoto, Satoshi Ishii, Koichirou Miyamoto, Kazunaga Horiuchi, Nobuyuki Aoki, ESR and low-temperature transport in multi-walled carbon nano-tube Physica B-condensed Matter. ,vol. 329, pp. 1542- 1543 ,(2003) , 10.1016/S0921-4526(02)02286-X
M.I. Chipara, D. Barb, P.V. Notingher, L. Georgescu, T. Sarbu, Spin probe investigation of molecular motions in polyepichlorohydrin: 1 Polymer. ,vol. 37, pp. 707- 712 ,(1996) , 10.1016/0032-3861(96)83160-0