Towards Improvement of Photovoltaic Performance of Aqueous Dye-sensitized Solar Cells by Tungsten-doped Mesoporous Nanobeads TiO2 Working Electrode

作者: Yanrong Guo , Tingting Zou , Qin Cheng , Binqing Jiao , Xiaoli Zhang

DOI: 10.1007/S11595-019-2008-Z

关键词:

摘要: Tungsten doped (W-doped) TiO2 mesoporous nanobeads, possessing high surface area and superior scattering effect, were used for photoanode preparation. The W-doping would induce a positive shift of the conduction band, enhance driving force electron injection collection efficiencies. electrochemical impedance spectra indicated retarded charge recombination increased diffusion length after W-doping. By fine-tuning concentration to 0.25%, aqueous DSCs produced significant improved open circuit voltage 712 mV short current 7.05 mA·cm-2, leading an overall power conversion efficiency 3.40% at 1 000 W·m-2 simulated irradiation, which is roughly 25% enhancement compared that without photoanode.

参考文章(30)
Jia Yu, Yu-Lin Yang, Rui-Qing Fan, Liang Li, Li-Guo Wei, Mechanism of performance enhancement via fluorine doped titanium dioxide nanoparticles in dye sensitized solar cells Journal of Fluorine Chemistry. ,vol. 176, pp. 71- 77 ,(2015) , 10.1016/J.JFLUCHEM.2015.05.015
M. Moradzaman, M.R. Mohammadi, H. Nourizadeh, Efficient dye-sensitized solar cells based on CNTs and Zr-doped TiO2 nanoparticles Materials Science in Semiconductor Processing. ,vol. 40, pp. 383- 390 ,(2015) , 10.1016/J.MSSP.2015.06.066
Liguo Wei, Yulin Yang, Xue Xia, Ruiqing Fan, Ting Su, Yan Shi, Jia Yu, Liang Li, Yanxia Jiang, Band edge movement in dye sensitized Sm-doped TiO2 solar cells: a study by variable temperature spectroelectrochemistry RSC Advances. ,vol. 5, pp. 70512- 70521 ,(2015) , 10.1039/C5RA15815J
Ting Su, Yulin Yang, Yong Na, Ruiqing Fan, Liang Li, Liguo Wei, Bin Yang, Wenwu Cao, An Insight into the Role of Oxygen Vacancy in Hydrogenated TiO2 Nanocrystals in the Performance of Dye-Sensitized Solar Cells ACS Applied Materials & Interfaces. ,vol. 7, pp. 3754- 3763 ,(2015) , 10.1021/AM5085447
Xiao Li Zhang, Zhipan Zhang, Dehong Chen, Peter Bäuerle, Udo Bach, Yi-Bing Cheng, Sensitization of nickel oxide: improved carrier lifetime and charge collection by tuning nanoscale crystallinity Chemical Communications. ,vol. 48, pp. 9885- 9887 ,(2012) , 10.1039/C2CC35018A
Yandong Duan, Nianqing Fu, Qian Zhang, Yanyan Fang, Xiaowen Zhou, Yuan Lin, None, Influence of Sn source on the performance of dye-sensitized solar cells based on Sn-doped TiO2 photoanodes: A strategy for choosing an appropriate doping source Electrochimica Acta. ,vol. 107, pp. 473- 480 ,(2013) , 10.1016/J.ELECTACTA.2013.06.085
Juan Bisquert, Physical electrochemistry of nanostructured devices Physical Chemistry Chemical Physics. ,vol. 10, pp. 49- 72 ,(2008) , 10.1039/B709316K
Juan Bisquert, Theory of the Impedance of Electron Diffusion and Recombination in a Thin Layer Journal of Physical Chemistry B. ,vol. 106, pp. 325- 333 ,(2002) , 10.1021/JP011941G
Xiao Li Zhang, Fuzhi Huang, Yang Chen, Yi-Bing Cheng, Rose Amal, None, An over 10% enhancement of dye-sensitized solar cell efficiency by tuning nanoparticle packing RSC Advances. ,vol. 3, pp. 17003- 17006 ,(2013) , 10.1039/C3RA42418A
Yao Liu, Anders Hagfeldt, Xu-Rui Xiao, Sten-Eric Lindquist, Investigation of influence of redox species on the interfacial energetics of a dye-sensitized nanoporous TiO2 solar cell Solar Energy Materials and Solar Cells. ,vol. 55, pp. 267- 281 ,(1998) , 10.1016/S0927-0248(98)00111-1