The Solvated Electron

作者: A. Mozumder

DOI: 10.1016/B978-012509390-3/50006-0

关键词:

摘要: This chapter briefly describes the solvated electron. Solvated electrons were first produced in liquid ammonia by dissolving sodium and potassium it; solution has an intense blue color. The provides three major methods of formation hydrated electron e h —the chemical, photochemical, radiation-chemical. aliphatic alcohols was discovered using pulse radiolysis soon after absorption spectrum covers entire visible region goes into UV IR regions. are known to be formed amines, amides, dimethyl sulfoxide, many other liquids. evolution s yields common shows considerable decay from picosecond nanosecond regime a comparable microsecond time scales. For yield scale observation, production itself is not related polarity. Thus, indeed been observed nonpolar liquids both at low temperatures room temperature.

参考文章(170)
C. D. Jonah, M. S. Matheson, J. R. Miller, E. J. Hart, Yield and decay of the hydrated electron from 100 ps to 3 ns The Journal of Physical Chemistry. ,vol. 80, pp. 1267- 1270 ,(1976) , 10.1021/J100553A001
MICHAEL ANBAR, Reactions of the Hydrated Electron AMERICAN CHEMICAL SOCIETY. pp. 55- 81 ,(1965) , 10.1021/BA-1965-0050.CH006
Edwin J. Hart, Sheffield Gordon, E. M. Fielden, Reaction of the Hydrated Electron with Water1 The Journal of Physical Chemistry. ,vol. 70, pp. 150- 156 ,(1966) , 10.1021/J100873A023
Klaus H. Schmidt, Sabine M. Ander, Formation and recombination of the hydronium ion (H3O+) and hydroxide in irradiated water The Journal of Physical Chemistry. ,vol. 73, pp. 2846- 2852 ,(1969) , 10.1021/J100843A009
Gerald L. Bolton, Gordon R. Freeman, Solvated electron reaction rates in alcohols and water. Solvent effect. [Reactions with dissolved gases] Journal of the American Chemical Society. ,vol. 98, pp. 6825- 6830 ,(1976) , 10.1021/JA00438A008
Uriel Sokolov, Gabriel Stein, Photolysis of Liquid Water at 1470 Å Journal of Chemical Physics. ,vol. 44, pp. 2189- 2192 ,(1966) , 10.1063/1.1726997
U. Schindewolf, Formation and Properties of Solvated Electrons Angewandte Chemie. ,vol. 7, pp. 190- 203 ,(1968) , 10.1002/ANIE.196801901