Adsorption of hydroxyacetone on pure ice surfaces
作者： Mélanie Petitjean , Maria Darvas , Sylvain Picaud , Pál Jedlovszky , Stéphane Le Calvé
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摘要: The adsorption of hydroxyacetone molecules at the surface ice is investigated by means flow-tube reactor measurements in temperature range: 213-253 K. number adsorbed per unit conventionally plotted as a function absolute gas concentration and compared to that previously obtained for acetone ethanol. enthalpy monolayer capacity are determined. In addition, molecular dynamics simulations performed support experimental results. However, it shown available interaction potential between not accurate enough allow robust detailed analysis process. Finally, rapid estimation partitioning phase shows densest clouds, up 29% could be on pure surfaces 203
sci-hub.se 参考文章(53)
H. Singh, Y. Chen, A. Staudt, D. Jacob, D. Blake, B. Heikes, J. Snow, Evidence from the Pacific troposphere for large global sources of oxygenated organic compounds Nature. ,vol. 410, pp. 1078- 1081 ,(2001) , 10.1038/35074067
Florent Dominé, Laurence Rey-Hanot, Adsorption isotherms of acetone on ice between 193 and 213 K Geophysical Research Letters. ,vol. 29, pp. 20- 1 ,(2002) , 10.1029/2002GL015078
Mélanie Petitjean, György Hantal, Coline Chauvin, Philippe Mirabel, Stéphane Le Calvé, Paul N. M. Hoang, Sylvain Picaud, Pál Jedlovszky, Adsorption of benzaldehyde at the surface of ice, studied by experimental method and computer simulation. Langmuir. ,vol. 26, pp. 9596- 9606 ,(2010) , 10.1021/LA100169H
Andrew J. Heymsfield, Robert M. Sabin, Cirrus crystal nucleation by homogeneous freezing of solution droplets Journal of the Atmospheric Sciences. ,vol. 46, pp. 2252- 2264 ,(1989) , 10.1175/1520-0469(1989)046<2252:CCNBHF>2.0.CO;2
O. Sokolov, J. P. D. Abbatt, Adsorption to ice of n-alcohols (ethanol to 1-hexanol), acetic acid, and hexanal Journal of Physical Chemistry A. ,vol. 106, pp. 775- 782 ,(2002) , 10.1021/JP013291M
Paula K. Hudson, Mark A. Zondlo, Margaret A. Tolbert, The interaction of methanol, acetone, and acetaldehyde with ice and nitric acid-doped ice: Implications for cirrus clouds Journal of Physical Chemistry A. ,vol. 106, pp. 2882- 2888 ,(2002) , 10.1021/JP012718M
N. Peybernès, S. Le Calvé, Ph. Mirabel, S. Picaud, P. N. M. Hoang, Experimental and Theoretical Adsorption Study of Ethanol on Ice Surfaces Journal of Physical Chemistry B. ,vol. 108, pp. 17425- 17432 ,(2004) , 10.1021/JP046983U
G. Schuster, J. N. Crowley, P. von Hessberg, N. Pouvesle, A. K. Winkler, Interaction of formic and acetic acid with ice surfaces between 187 and 227 K. Investigation of single species- and competitive adsorption. Physical Chemistry Chemical Physics. ,vol. 10, pp. 2345- 2355 ,(2008) , 10.1039/B800831K
Halbert Carmichael, What the standard state doesn't say about temperature and phase Journal of Chemical Education. ,vol. 53, pp. 695- ,(1976) , 10.1021/ED053P695
M. Petitjean, E. Reyès-Pérez, D. Pérez, Ph. Mirabel, S. Le Calvé, Vapor Pressure Measurements of Hydroxyacetaldehyde and Hydroxyacetone in the Temperature Range (273 to 356) K Journal of Chemical & Engineering Data. ,vol. 55, pp. 852- 855 ,(2010) , 10.1021/JE9004905