Temperature Dependence of a Kelvin Model for Binary Nucleation†

摘要: The temperature dependence of binary nucleation rates was studied using several different models for the cluster evaporation rates. were found detailed balance relations in combination with three constrained equilibrium concentrations:  classical Reiss model, self-consistent model Wilemski and Wyslouzil, new Kelvin model. latter two are modifications liquid droplet expression concentrations. steady state kinetics equations numerically solved technique matrix inversion by patitioning. Numerous test calculations made ideal ethanol−hexanol system. We that gave most realistic examined. An analytical rate accurately reproduces numerical results is also presented.