A Simple and Efficient Chemical Decontamination of Sulfur Mustard (HD) Using 1,8-Diazabicyclo[5,4,0]Undec-7-Ene Hydrobromide-Perbromide
作者： D. Raghavender Goud , Mamta Sharma , M. V. S. Suryanarayana
DOI: 10.1080/10426507.2011.600742
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摘要: Abstract A simple and efficient chemical decontamination method was developed against sulfur mustard (HD), an extremely toxic persistent warfare agent. The involves treatment of agent HD its simulants, i.e., methyl p-tolyl sulfide, 2-chloroethyl phenyl ethyl with 1,8-diazabicyclo[5,4,0]undec-7-ene hydrobromide-perbromide at room temperature in 1:3 acetonitrile–water system as well aqueous medium. reagent has efficiency to oxidize a controlled manner form nontoxic sulfoxide avoiding overoxidation the sulfone. Reaction products oxidation were isolated analyzed by gas chromatography-mass spectrometry 1H NMR.
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