Effect of silica on the electrochemical characteristics of the plasticized polymer electrolytes based on the P(AN-co-MMA) copolymer
作者： K Lee
DOI: 10.1016/S0167-2738(00)00708-6
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摘要: Composite polymer electrolyte films consisting of poly (acrylonitrile-co-methyl methacrylate)(P (AN-co-MMA)), EC–PC, LiClO4 salts, and also silica particles have been prepared, and their electrochemical properties were studied. A maximum in the ion conductivity was found for the plasticized polymer electrolyte containing 10 wt% silica with EC–PC and was 1.7× 10− 4 S/cm at− 15° C and 1.9× 10− 3 S/cm at 25° C. The reduction in Tg of the plasticizer-rich phase in the composite polymer electrolytes due to the interaction …
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