Fe(NO 3 ) 3 -Catalyzed Monoterpene Oxidation by Hydrogen Peroxide: An Inexpensive and Environmentally Benign Oxidative Process

作者: Danieli Marcolan Carari , Márcio José da Silva

DOI: 10.1007/S10562-013-1189-X

关键词:

摘要: Simple Fe(NO3)2·9H2O was demonstrated to be able catalyze the oxidation of monoterpenes by hydrogen peroxide in methyl alcohol solution. Compared with previous iron-catalyzed methods, present procedure avoids use stabilizing ligands, additives, and corrosive organic oxidants. A novel, simple highly efficient catalyst system developed for oxidizing into a valuable derivates using peroxide, an environmentally friendly oxidant. Possible steps involved Fe(III)-catalyzed β-pinene myrtenol ether

参考文章(34)
Agathe Christine Mayer, Carsten Bolm, Sabine Laschat, Volker Rabe, Angelika Baro, Olga Garca Mancheo, Iron‐Catalyzed Oxidation Reactions Iron Catalysis in Organic Chemistry: Reactions and Applications. pp. 73- 123 ,(2008) , 10.1002/9783527623273.CH3
Analía L. Cánepa, Corina M. Chanquía, Griselda A. Eimer, Sandra G. Casuscelli, Oxidation of olefins employing mesoporous molecular sieves modified with copper Applied Catalysis A-general. ,vol. 462, pp. 8- 14 ,(2013) , 10.1016/J.APCATA.2013.04.031
F. Maspero, U. Romano, Oxidation of Alcohols with H2O2 Catalyzed by Titanium Silicalite-1 Journal of Catalysis. ,vol. 146, pp. 476- 482 ,(1994) , 10.1006/JCAT.1994.1085
Lawrence Que, William B. Tolman, Biologically inspired oxidation catalysis Nature. ,vol. 455, pp. 333- 340 ,(2008) , 10.1038/NATURE07371
Anand Pariyar, Suranjana Bose, Achintesh Narayan Biswas, Purak Das, Pinaki Bandyopadhyay, Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides Catalysis Communications. ,vol. 32, pp. 23- 27 ,(2013) , 10.1016/J.CATCOM.2012.11.026
Enio J. Leão Lana, Kelly A. da Silva Rocha, Ivan V. Kozhevnikov, Elena V. Gusevskaya, Synthesis of 1,8-cineole and 1,4-cineole by isomerization of α-terpineol catalyzed by heteropoly acid Journal of Molecular Catalysis A: Chemical. ,vol. 259, pp. 99- 102 ,(2006) , 10.1016/J.MOLCATA.2006.05.064
Paul T Anastas, Lauren B Bartlett, Mary M Kirchhoff, Tracy C Williamson, None, The role of catalysis in the design, development, and implementation of green chemistry Catalysis Today. ,vol. 55, pp. 11- 22 ,(2000) , 10.1016/S0920-5861(99)00222-9
Alexandre Almeida de Oliveira, Milene Lopes da Silva, Márcio José da Silva, Palladium-Catalysed Oxidation of Bicycle Monoterpenes by Hydrogen Peroxide in Acetonitrile Solutions: A Metal Reoxidant-Free and Environmentally Benign Oxidative Process Catalysis Letters. ,vol. 130, pp. 424- 431 ,(2009) , 10.1007/S10562-009-9970-6
Márcio J da Silva, Patricia Robles-Dutenhefner, Luciano Menini, Elena V Gusevskaya, None, Cobalt catalyzed autoxidation of monoterpenes in acetic acid and acetonitrile solutions Journal of Molecular Catalysis A-chemical. ,vol. 201, pp. 71- 77 ,(2003) , 10.1016/S1381-1169(03)00180-8