Fourier transform two-dimensional electronic-vibrational spectroscopy using an octave-spanning mid-IR probe.
作者： James D. Gaynor , Trevor L. Courtney , Madhumitha Balasubramanian , Munira Khalil
DOI: 10.1364/OL.41.002895
关键词:
摘要: The development of coherent Fourier transform two-dimensional electronic-vibrational (2D EV) spectroscopy with acousto-optic pulse-shaper-generated near-UV pump pulses and an octave-spanning broadband mid-IR probe pulse is detailed. A 2D EV spectrum a silicon wafer demonstrates the full experimental capability this experiment, dissolved hexacyanoferrate establishes viability our experiment for studying condensed phase molecular ensembles.
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