作者: S. P. Moulik , S. Ray , A. R. Das
DOI: 10.1007/BF01638146
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摘要: Proton transfer complexing equilibrium in aqueous media between p-nitrosalicylic acid and ethylenediamine has been studied presence of CTAB, SDS, TX-100 PEG, where CTAB SDS have observed to enhance the reaction whereas, PEG suppressed it. Salts like KCl NaCl got antagonistic effects on activities SDS. The proton phenomenon can help determining cmc additives. constants process determined standard thermodynamic parameters, ΔH°, JG' andΔ S° derived. shown ‘isothermodynamic’ linear enthalpy-entropy relationship.