Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase
作者： James M. Camara , Thomas B. Rauchfuss
DOI: 10.1038/NCHEM.1180
关键词:
摘要: The fastest catalysts in nature for producing and oxidizing hydrogen are [FeFe]-hydrogenases, which make use of an extra one-electron redox equivalent from iron-sulfur cluster that is outside the core. Now, a ferrocene-based ligand oxidizes at mild potential performs this cluster's role excellent synthetic hydrogenase model.
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