SnCo–CMK nanocomposite with improved electrochemical performance for lithium-ion batteries

作者: Lingxing Zeng , Cuilin Deng , Cheng Zheng , Heyuan Qiu , Qingrong Qian

DOI: 10.1016/J.MATERRESBULL.2015.07.004

关键词:

摘要: Abstract In the present work, SnCo–CMK nanocomposite was successfully synthesized for first time via a simple nanocasting route by using mesoporous carbon as nano-reactor. The then characterized means of X-ray diffraction (XRD), thermogravimetric analysis (TG), N2 adsorption–desorption, scanning and transmission electron microscopy (SEM/TEM) respectively. Furthermore, exhibited large reversible capacities, excellent cycling stability enhanced rate capability when employed an anode material lithium-ion batteries. A capacity 562 mA h g−1 obtained after 60 cycles at current density 0.1 A g−1 which is attributed to structure ‘meso-nano’ composite. This unique ensures intimate contact between CMK SnCo nanoparticles, buffers volume expansion prevents aggregation nanoparticles during cycling, leading capability.

参考文章(42)
Lingxing Zeng, Cheng Zheng, Jingchao Xi, Hailong Fei, Mingdeng Wei, Composites of V2O3–ordered mesoporous carbon as anode materials for lithium-ion batteries Carbon. ,vol. 62, pp. 382- 388 ,(2013) , 10.1016/J.CARBON.2013.06.021
H. Zhou, S. Zhu, M. Hibino, I. Honma, M. Ichihara, Lithium Storage in Ordered Mesoporous Carbon (CMK‐3) with High Reversible Specific Energy Capacity and Good Cycling Performance Advanced Materials. ,vol. 15, pp. 2107- 2111 ,(2003) , 10.1002/ADMA.200306125
Guoqing Fang, Weiwei Liu, Shingo Kaneko, Bingbo Xia, Hongdan Sun, Junwei Zheng, Decheng Li, Preparation, microstructure, and electrochemical properties of Sn-Co-C anode materials using composited carbon sources Journal of Solid State Electrochemistry. ,vol. 17, pp. 2521- 2529 ,(2013) , 10.1007/S10008-013-2137-9
Fangwei Zhan, Hui Zhang, Yue Qi, Jiazheng Wang, Ning Du, Deren Yang, Electrochemical synthesis of SnCo alloy shells on orderly rod-shaped Cu current collectors as anode materials for lithium-ion batteries with enhanced performance Journal of Alloys and Compounds. ,vol. 570, pp. 119- 124 ,(2013) , 10.1016/J.JALLCOM.2013.02.154
Lingxing Zeng, Qunfang Li, Dianping Tang, Guonan Chen, Mingdeng Wei, Metal platinum-wrapped mesoporous carbon for sensitive electrochemical immunosensing based on cyclodextrin functionalized graphene nanosheets Electrochimica Acta. ,vol. 68, pp. 158- 165 ,(2012) , 10.1016/J.ELECTACTA.2012.02.045
Chu Liang, Mingxia Gao, Hongge Pan, Yongfeng Liu, Mi Yan, Lithium alloys and metal oxides as high-capacity anode materials for lithium-ion batteries Journal of Alloys and Compounds. ,vol. 575, pp. 246- 256 ,(2013) , 10.1016/J.JALLCOM.2013.04.001
Shinae Jun, Sang Hoon Joo, Ryong Ryoo, Michal Kruk, Mietek Jaroniec, Zheng Liu, Tetsu Ohsuna, Osamu Terasaki, Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure Journal of the American Chemical Society. ,vol. 122, pp. 10712- 10713 ,(2000) , 10.1021/JA002261E
Xiulei Ji, Kyu Tae Lee, Linda F. Nazar, A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Nature Materials. ,vol. 8, pp. 500- 506 ,(2009) , 10.1038/NMAT2460
Dongyuan Zhao, Qisheng Huo, Jianglin Feng, Bradley F. Chmelka, Galen D. Stucky, Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures Journal of the American Chemical Society. ,vol. 120, pp. 6024- 6036 ,(1998) , 10.1021/JA974025I