Intumescent Nanocoating Extinguishes Flame on Fabric Using Aqueous Polyelectrolyte Complex Deposited in Single Step
作者： Amanda A. Cain , Shannon Murray , Kevin M. Holder , Craig R. Nolen , Jaime C. Grunlan
关键词:
摘要: In an effort to produce a more effective and environmentally friendly flame-retardant (FR) treatment for cotton fabric, two-ingredient aqueous polyelectrolyte complex was used create one-step deposition system. This easy-to-apply nanocoating, made with nitrogen-rich phosphorous-rich polyelectrolytes, maintains the fabric's weave structure by spontaneously coating individual fibers. Coating pick-up is reproducible function of both soak time pot life complex. From microscale calorimetry data, fabric soaked only 1min in this “OnePot” flame-retarding exhibits 52.7% reduction total heat release, 2.3 wt% added.
sci-hub.se 参考文章(37)
Christine Wandrey, Gabriela Grigorescu, David Hunkeler, Study of polyelectrolyte complex formation applying the synthetic boundary technique of analytical ultracentrifugation Progress in colloid and polymer science. ,vol. 119, pp. 84- 91 ,(2002) , 10.1007/3-540-44672-9_13
Dan H. Marsh, D. Jason Riley, David York, Andrew Graydon, Sorption of inorganic nanoparticles in woven cellulose fabrics Particuology. ,vol. 7, pp. 121- 128 ,(2009) , 10.1016/J.PARTIC.2009.01.004
Kadir Apaydin, Abdelghani Laachachi, Vincent Ball, Maude Jimenez, Serge Bourbigot, Valérie Toniazzo, David Ruch, Polyallylamine–montmorillonite as super flame retardant coating assemblies by layer-by layer deposition on polyamide Polymer Degradation and Stability. ,vol. 98, pp. 627- 634 ,(2013) , 10.1016/J.POLYMDEGRADSTAB.2012.11.006
P. Maarten Biesheuvel, Martien A. Cohen Stuart, Electrostatic free energy of weakly charged macromolecules in solution and intermacromolecular complexes consisting of oppositely charged polymers. Langmuir. ,vol. 20, pp. 2785- 2791 ,(2004) , 10.1021/LA036204L
M. Jimenez, S. Duquesne, S. Bourbigot, Intumescent fire protective coating: Toward a better understanding of their mechanism of action Thermochimica Acta. ,vol. 449, pp. 16- 26 ,(2006) , 10.1016/J.TCA.2006.07.008
J. A. Rhys, Intumescent coatings and their uses Fire and Materials. ,vol. 4, pp. 154- 156 ,(1980) , 10.1002/FAM.810040308
Galina Laufer, Christopher Kirkland, Alexander B. Morgan, Jaime C. Grunlan, Intumescent Multilayer Nanocoating, Made with Renewable Polyelectrolytes, for Flame-Retardant Cotton Biomacromolecules. ,vol. 13, pp. 2843- 2848 ,(2012) , 10.1021/BM300873B
A.R. Horrocks, B.K. Kandola, P.J. Davies, S. Zhang, S.A. Padbury, Developments in flame retardant textiles – a review Polymer Degradation and Stability. ,vol. 88, pp. 3- 12 ,(2005) , 10.1016/J.POLYMDEGRADSTAB.2003.10.024
P. Bertrand, A. Jonas, A. Laschewsky, R. Legras, Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces: suitable materials, structure and properties Macromolecular Rapid Communications. ,vol. 21, pp. 319- 348 ,(2000) , 10.1002/(SICI)1521-3927(20000401)21:7<319::AID-MARC319>3.0.CO;2-7
Sami Ullah, Faiz Ahmad, P. S. M. Megat Yusoff, Effect of boric acid and melamine on the intumescent fire-retardant coating composition for the fire protection of structural steel substrates Journal of Applied Polymer Science. ,vol. 128, pp. 2983- 2993 ,(2013) , 10.1002/APP.38318