UTICAJ TEMPERATURE NA PIROLIZU OTPADNE PLASTIKE U REAKTORU SA FIKSNIM SLOJEM

作者: Sasa Papuga , Petar Gvero , Ljiljana Vukic

DOI: 10.7251/GHTE1410035P

关键词:

摘要: Piroliza, kao jedna od tehnika hemijske reciklaže plasticnih materijala, danas izaziva sve veca intersovanja ekoloski i ekonomski prihvaljiva opcija obrade otpadnih materijala. Istraživanja ovih procesa se provode pri razlicitim eksperimentalnim uslovima, u vrstama reaktora sa sirovinama, sto cini poređenje direktnu primjenu procesnih parametara dosta složenim. U ovom radu dati su rezultati istraživanja uticaja temperature, intervalu od  450°C do 525°C, na prinos pirolize smjese otpadne plastike sastavu: polipropilen 40%, polietilen niske gustine 35% visoke 25%. provedena pilot reaktoru fiksnim slojem koji je razvijen za ovu namjenu. Rezultati provedenih pokazuju da temperaturi 500°C  postiže potpuna konverzija sirovine vremenu 45 min, uz maksimalni pirolitickog ulja 32,80%, gasovitih produkata 65,75% cvrsti ostatak 1,46%. Sa daljim porastom temperature raste produkata, racun smanjenja prinosa ulja. Dobijeno piroliticko ulje ima visoku toplotnu moc (45,96 МЈ/kg), te tom pogledu potencijal primjene alternativno gorivo.

参考文章(23)
Saša Papuga, Ljiljana Vukić, Igor Musić, Petar Gvero, PRELIMINARY RESEARCH OF WASTE BIOMASS AND PLASTIC PYROLYSIS PROCESS Contemporary materials. ,vol. 4, pp. 76- 83 ,(2013) , 10.7251/736
Paul T. Williams, Waste treatment and disposal ,(1998)
Elham Khaghanikavkani, Mohammed Mehdi Farid, None, Thermal Pyrolysis of Polyethylene: Kinetic Study Energy Science and Technology. ,vol. 2, pp. 1- 10 ,(2011) , 10.3968/J.EST.1923847920110201.597
S.M. Al-Salem, P. Lettieri, Kinetics of Polyethylene Terephthalate (PET)and Polystyrene (PS) Dynamic Pyrolysis World Academy of Science, Engineering and Technology, International Journal of Chemical, Molecular, Nuclear, Materials and Metallurgical Engineering. ,vol. 4, pp. 402- 410 ,(2010)
Paula A. Costa, Filomena J. Pinto, Ana. M. Ramos, Ibrahim K. Gulyurtlu, Isabel A. Cabrita, Maria. S. Bernardo, Kinetic Evaluation of the Pyrolysis of Polyethylene Waste Energy & Fuels. ,vol. 21, pp. 2489- 2498 ,(2007) , 10.1021/EF070115P
Limin Zhou, Yiping Wang, Qunwu Huang, Junqing Cai, Thermogravimetric characteristics and kinetic of plastic and biomass blends co-pyrolysis Fuel Processing Technology. ,vol. 87, pp. 963- 969 ,(2006) , 10.1016/J.FUPROC.2006.07.002
V.I Sharypov, N.G Beregovtsova, B.N Kuznetsov, L Membrado, V.L Cebolla, N Marin, J.V Weber, Co-pyrolysis of wood biomass and synthetic polymers mixtures. Part III: Characterisation of heavy products Journal of Analytical and Applied Pyrolysis. ,vol. 67, pp. 325- 340 ,(2003) , 10.1016/S0165-2370(02)00071-2
A. Adrados, I. de Marco, B.M. Caballero, A. López, M.F. Laresgoiti, A. Torres, Pyrolysis of plastic packaging waste: A comparison of plastic residuals from material recovery facilities with simulated plastic waste. Waste Management. ,vol. 32, pp. 826- 832 ,(2012) , 10.1016/J.WASMAN.2011.06.016
G. Elordi, G. Lopez, M. Olazar, R. Aguado, J. Bilbao, Product distribution modelling in the thermal pyrolysis of high density polyethylene. Journal of Hazardous Materials. ,vol. 144, pp. 708- 714 ,(2007) , 10.1016/J.JHAZMAT.2007.01.101
N Kiran, E Ekinci, C.E Snape, Recyling of plastic wastes via pyrolysis Resources Conservation and Recycling. ,vol. 29, pp. 273- 283 ,(2000) , 10.1016/S0921-3449(00)00052-5