摘要: The dp-polarographic and stripping voltammetric behaviour of germanium(IV) in the presence various supporting electrolytes is discussed. Moreover, a highly sensitive adsorptive technique has been developed. determination based on accumulation germanium(IV)-diol complexes by adsorption at hanging mercury drop electrode, followed cathodic voltammetry. Suitable for complex forming reaction are catechol (1,2-dihydroxybenzol) pyrogallol (1,2,3-trihydroxybenzol). By using detection limit 0.1 ng ml−1 with standard deviation ±13%. A multistage combined procedure voltammetry described germanium traces ginseng garlic. results compared those extraction-spectrophotometry atomic absorption spectrometry.
springer.com
sci-hub.se 参考文章(27)
Janusz Gołaś, Zygmunt Kowalski, Some electroanalytical aspects of using pulse polarography for determination of Ge(IV) Mikrochimica Acta. ,vol. 82, pp. 399- 408 ,(1984) , 10.1007/BF01198686
D. Cozzi, S. Vivarelli, Die Oxydation des Germaniums (2) an der Quecksilbertropfelektrode und ihre analytische Anwendung Mikrochimica Acta. ,vol. 36, pp. 594- 600 ,(1951) , 10.1007/BF01460858
W. Wendl, Investigations on chemical reactions in graphite furnace AAS Fresenius Journal of Analytical Chemistry. ,vol. 323, pp. 726- 729 ,(1986) , 10.1007/BF00467066
R. Kalvoda, N. Konopik, Oscillopolarographische Mikrobestimmung von Germanium Fresenius Journal of Analytical Chemistry. ,vol. 244, pp. 30- 35 ,(1969) , 10.1007/BF01198028
D. Thorburn Burns, D. Dadgar, Investigations on the determination of germanium in organogermanium compounds using carbon furnace atomisation The Analyst. ,vol. 107, pp. 452- 455 ,(1982) , 10.1039/AN9820700452
Zenon J. Karpiński, Andrzej Połosak, Zenon Kublik, Anodic stripping voltammetry of germanium at the hanging mercury drop electrode Analytica Chimica Acta. ,vol. 120, pp. 55- 64 ,(1980) , 10.1016/S0003-2670(01)84347-6
Y Sohrin, Determination of germanium by graphite-furnace atomic-absorption spectrometry. Talanta. ,vol. 34, pp. 341- 344 ,(1987) , 10.1016/0039-9140(87)80043-7
H. Vandebroek, F. Verbeek, Determination of Germanium in Zinc by Differential Cathode Ray Polarography Analytical Letters. ,vol. 5, pp. 317- 328 ,(1972) , 10.1080/00032717208062886
Marek. Studnicki, Determination of germanium, vanadium, and titanium by carbon furnace atomic absorption spectrometry Analytical Chemistry. ,vol. 52, pp. 1762- 1764 ,(1980) , 10.1021/AC50061A051
Gh Sauvenier, G Duyckaerts, Étude du comportement polarographique de Ge(IV) Analytica Chimica Acta. ,vol. 13, pp. 396- 403 ,(1955) , 10.1016/S0003-2670(00)87963-5