Effect of radical polymer cathode thickness on the electrochemical performance of organic radical battery
作者： J KIM , G CHERUVALLY , J CHOI , J AHN , S LEE
DOI: 10.1016/J.SSI.2007.09.009
关键词:
摘要: Abstract The influence of cathode thickness on the electrochemical performance an organic radical battery (ORB) with polymer poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA) as active material is presented. ORB consists lithium metal anode and PTMA content 40 wt.%. An increase in results a decrease specific capacity discharge voltage cell electrode/electrolyte interfacial resistance. best achieved thin 17 μm that shows nearly 100% utilization (∼ 111 mAh/g) at current densities up to 1.0 mA/cm2. exhibits excellent high-rate capability cycle characteristics stable impedance behavior intact structure cycling. demonstrate high can be from non-conductive higher by using properly prepared consisting uniform, nanometer range coating layer conductive carbon particles.
elsevier.com
sci-hub.se 参考文章(11)
Kentaro Nakahara, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, Elton J. Cairns, High-rate capable organic radical cathodes for lithium rechargeable batteries Journal of Power Sources. ,vol. 165, pp. 870- 873 ,(2007) , 10.1016/J.JPOWSOUR.2006.11.045
Yukiko Morioka, Masahiro Suguro, Masaharu Satoh, Elton J. Cairns, Kentaro Nakahara, Shigeyuki Iwasa, Jiro Iriyama, Electrochemical and spectroscopic measurements for stable nitroxyl radicals Electrochimica Acta. ,vol. 52, pp. 921- 927 ,(2006) , 10.1016/J.ELECTACTA.2006.06.028
Kentaro Nakahara, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, Elton J. Cairns, Cell properties for modified PTMA cathodes of organic radical batteries Journal of Power Sources. ,vol. 165, pp. 398- 402 ,(2007) , 10.1016/J.JPOWSOUR.2006.11.044
Zorica Veksli, Wilmer G. Miller, The Effect of Good Solvents on Molecular Motion of Nitroxide Free Radicals in Covalently Labeled Polystyrene and Poly(methyl methacrylate) Macromolecules. ,vol. 10, pp. 686- 692 ,(1977) , 10.1021/MA60057A038
Kentaro Nakahara, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, Elton J. Cairns, Al-laminated film packaged organic radical battery for high-power applications Journal of Power Sources. ,vol. 163, pp. 1110- 1113 ,(2007) , 10.1016/J.JPOWSOUR.2006.10.003
Finlay MacCorquodale, Joe A. Crayston, John C. Walton, D.Jim Worsfold, Synthesis and electrochemical characterisation of poly(tempoacrylate) Tetrahedron Letters. ,vol. 31, pp. 771- 774 ,(1990) , 10.1016/S0040-4039(00)94625-2
Hiroyuki Nishide, Shigeyuki Iwasa, Yong-Jin Pu, Takeo Suga, Kentaro Nakahara, Masaharu Satoh, Organic radical battery: nitroxide polymers as a cathode-active material Electrochimica Acta. ,vol. 50, pp. 827- 831 ,(2004) , 10.1016/J.ELECTACTA.2004.02.052
Hui-qiao Li, Ying Zou, Yong-yao Xia, A study of nitroxide polyradical/activated carbon composite as the positive electrode material for electrochemical hybrid capacitor Electrochimica Acta. ,vol. 52, pp. 2153- 2157 ,(2007) , 10.1016/J.ELECTACTA.2006.08.031
K Nakahara, S Iwasa, M Satoh, Y Morioka, J Iriyama, M Suguro, E Hasegawa, Rechargeable batteries with organic radical cathodes Chemical Physics Letters. ,vol. 359, pp. 351- 354 ,(2002) , 10.1016/S0009-2614(02)00705-4
Toru Katsumata, Masaharu Satoh, Jun Wada, Masashi Shiotsuki, Fumio Sanda, Toshio Masuda, Polyacetylene and Polynorbornene Derivatives Carrying TEMPO. Synthesis and Properties as Organic Radical Battery Materials Macromolecular Rapid Communications. ,vol. 27, pp. 1206- 1211 ,(2006) , 10.1002/MARC.200600286