Translational spectroscopy of electron impact dissociation of HF by doppler profile measurements of Balmer-α emission
作者： M. Ohno , N. Kouchi , K. Ito , N. Oda , Y. Hatano
DOI: 10.1016/0301-0104(81)80043-2
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摘要: Abstract The Doppler profiles of the Balmer-α emission by electron impact on HF have been investigated through varying energy using an etalon-grating monochromator with a high resolving power. spectral consist three components, which indicates that there are kinds precursors leading to H*(3) contributing emission. average kinetic is obtained for each component. From discussions and their dissociation processes, observed ascribed Rydberg states (≈18 eV), doubly excited (≈23 eV) inner shell (≈40 eV).
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H.A. van Sprang, F.J. de Heer, A study of the emission spectrum of HF excited by electrons Chemical Physics. ,vol. 33, pp. 73- 78 ,(1978) , 10.1016/0301-0104(78)87072-4
Kenji Ito, Nobou Oda, Yoshihiko Hatano, Toshio Tsuboi, The electron energy dependence of the doppler profiles of the Balmer-α emission from H2, D2, CH4 and other simple hydrocarbons by electron impact principles and practice of constraint programming. ,vol. 21, pp. 203- 210 ,(1977) , 10.1016/0301-0104(77)80014-1
Hans Lischka, A note on the AB initio calculation of intermolecular potentials: the HF dimer Chemical Physics Letters. ,vol. 66, pp. 108- 110 ,(1979) , 10.1016/0009-2614(79)80378-4
C.R. Brundle, Ionization and dissociation energies of HF and DF and their bearing on Do0 (F2) Chemical Physics Letters. ,vol. 7, pp. 317- 322 ,(1970) , 10.1016/0009-2614(70)80171-3
M.S. Banna, D.A. Shirley, Molecular photoelectron spectroscopy at 132.3 eV. Methane, the fluorinated methanes and hydrogen fluoride Chemical Physics Letters. ,vol. 33, pp. 441- 446 ,(1975) , 10.1016/0009-2614(75)85748-4
H.A. van Sprang, H.H. Brongersma, F.J. de Heer, An analysis of some optically allowed and optically forbidden excitation processes leading to dissociation Chemical Physics. ,vol. 38, pp. 277- 284 ,(1979) , 10.1016/0301-0104(79)89001-1
J. Berkowitz, W. A. Chupka, P. M. Guyon, J. H. Holloway, R. Spohr, Photoionization Mass Spectrometric Study of F2, HF, and DF The Journal of Chemical Physics. ,vol. 54, pp. 5165- 5180 ,(1971) , 10.1063/1.1674811
Kenji Ito, Nobuo Oda, Yoshihiko Hatano, Toshio Tsuboi, Doppler profile measurements of balmer-α radiation by electron impact on H2 Chemical Physics. ,vol. 17, pp. 35- 43 ,(1976) , 10.1016/0301-0104(76)85005-7
G. Di Lonardo, A. E. Douglas, The Electronic Spectrum of HF. I. The B1Σ+–X1Σ+ Band System Canadian Journal of Physics. ,vol. 51, pp. 434- 445 ,(1973) , 10.1139/P73-057
N. Kouchi, K. Ito, Y. Hatano, N. Oda, T. Tsuboi, Translational spectroscopy of electron-impact dissociative excitation of H2O and D2O by doppler profile measurements of Balmer-α emission Chemical Physics. ,vol. 36, pp. 239- 245 ,(1979) , 10.1016/0301-0104(79)85009-0