Metal and polymer-mediated synthesis of porous crystalline hydroxyapatite nanocomposites for environmental remediation
作者： Danushika C. Manatunga , Rohini M. de Silva , K. M. Nalin de Silva , Nuwan de Silva , E. V. A. Premalal
DOI: 10.1098/RSOS.171557
关键词:
摘要: This study was focused on the preparation of metal and polymer-mediated porous crystalline hydroxyapatite (HAp) nanocomposites for environmental applications. Four different nano HAp systems were synthesized, namely, microwave irradiated (M1), Zn doped (M2), Mg-doped (M3) sodium alginate incorporated (M4), characterized using X-ray diffraction (XRD), Fourier transform infra-red spectroscopy, scanning electron microscopy, transmission atomic force nuclear magnetic resonance (NMR), fluorescence, thermogravimetric analysis Brunauer–Emmett–Teller (BET) analyses. Systems M1–M4 showed morphologies similar to coral shapes, polymer-like interconnected structures, sponges feathery mycelium assemblies. Using XRD, selected area patterns 1 H 31 P CP/MAS solid-state NMR studies, crystallinity variation observed from highest lowest in order M4 > M1 > M3 > M2. Surface estimates BET isotherm reflected surface M3, M1 > M2 > M4. used as potential adsorbent materials removal containing azo dye aqueous system. Adsorption data correlated Freundlich Langmuir models. According results, capacity 212.8 mg g −1 exhibited by M4 having like morphology with groups. highlights possibility developing effective contaminants environment.
royalsocietypublishing.org
sci-hub.se 参考文章(72)
Aditya Rawal, NMR investigations of biological and synthetic phosphate-based nanocomposites Iowa State University. ,(2007) , 10.31274/RTD-180813-16934
Masahiro Okada, Takuya Matsumoto, Synthesis and modification of apatite nanoparticles for use in dental and medical applications Japanese Dental Science Review. ,vol. 51, pp. 85- 95 ,(2015) , 10.1016/J.JDSR.2015.03.004
Chuang Zhao, Jianhui Guo, Qing Yang, Lei Tong, Jingwei Zhang, Jiwei Zhang, Chunhong Gong, Jingfang Zhou, Zhijun Zhang, Preparation of magnetic Ni@graphene nanocomposites and efficient removal organic dye under assistance of ultrasound Applied Surface Science. ,vol. 357, pp. 22- 30 ,(2015) , 10.1016/J.APSUSC.2015.08.031
Bing Feng, Xiaoyong Xu, Wei Xu, Gang Zhou, Jingguo Hu, Yali Wang, Zhijia Bao, Self-assembled 3D ACF–rGO–TiO2 composite as efficient and recyclable spongy adsorbent for organic dye removal Materials & Design. ,vol. 83, pp. 522- 527 ,(2015) , 10.1016/J.MATDES.2015.06.061
Soyeon Park, Allan Gomez-Flores, Yong Sik Chung, Hyunjung Kim, Removal of Cadmium and Lead from Aqueous Solution by Hydroxyapatite/Chitosan Hybrid Fibrous Sorbent: Kinetics and Equilibrium Studies Journal of Chemistry. ,vol. 2015, pp. 1- 12 ,(2015) , 10.1155/2015/396290
Avijit Guha, Arvind Sinha, Surface Mineralization of Hydrogels Through Octacalcium Phosphate International Journal of Applied Ceramic Technology. ,vol. 8, pp. 540- 546 ,(2011) , 10.1111/J.1744-7402.2010.02543.X
Abideen Idowu Adeogun, Ramesh Balakrishnan Babu, One-step synthesized calcium phosphate-based material for the removal of alizarin S dye from aqueous solutions: isothermal, kinetics, and thermodynamics studies Applied Nanoscience. pp. 1- 13 ,(2015) , 10.1007/S13204-015-0484-9
Humberto A Monreal Romero, José Mora Ruacho, Carlos A Martínez Pérez, Perla E García Casillas, None, Synthesis of Hydroxyapatite Nanoparticles in Presence of a Linear Polysaccharide Journal: Materials. ,vol. 2013, pp. 1- 5 ,(2013) , 10.1155/2013/683268
Liuyun Jiang, Yubao Li, Xuejiang Wang, Li Zhang, Jiqiu Wen, Mei Gong, Preparation and properties of nano-hydroxyapatite/chitosan/carboxymethyl cellulose composite scaffold Carbohydrate Polymers. ,vol. 74, pp. 680- 684 ,(2008) , 10.1016/J.CARBPOL.2008.04.035
Y.X. Pang, X. Bao, Influence of temperature, ripening time and calcination on the morphology and crystallinity of hydroxyapatite nanoparticles Journal of The European Ceramic Society. ,vol. 23, pp. 1697- 1704 ,(2003) , 10.1016/S0955-2219(02)00413-2