Reaction of an introverted carboxylic acid with carbodiimide
作者： Tetsuo Iwasawa , Paul Wash , Christoph Gibson , Julius Rebek
DOI: 10.1016/J.TET.2007.03.075
关键词:
摘要: Abstract The reaction of carboxylic acids with carbodiimides is reviewed, and an ‘introverted’ acid proposed as a means trapping reactive intermediates along the pathway. introverted cavitand function directed toward floor cavity. Its diisopropyl carbodiimide gives covalent adduct that either elusive O -acylisourea or commonly encountered N -acylurea.
elsevier.com
sci-hub.se 参考文章(43)
Donald J Cram, Jane M Cram, Container Molecules and their Guests ,(1994)
Xiang Wang, Huifang Chen, Hang Yin, S. Samuel Kim, Seang Lin Tan, Roger G. Gosden, Fertility after intact ovary transplantation Nature. ,vol. 415, pp. 385- 385 ,(2002) , 10.1038/415385A
D. S. Kemp, Konstantinos S. Petrakis, Synthesis and conformational analysis of cis,cis-1,3,5-trimethylcyclohexane-1,3,5-tricarboxylic acid Journal of Organic Chemistry. ,vol. 13, pp. 5140- 5143 ,(1981) , 10.1021/JO00338A014
Julius Rebek, Luann Marshall, Raymond Wolak, Kevin Parris, Mary Killoran, Ben Askew, David Nemeth, N. Islam, Convergent functional groups: synthetic and structural studies Journal of the American Chemical Society. ,vol. 107, pp. 7476- 7481 ,(1985) , 10.1021/JA00311A042
Adam R Renslo, Julius Rebek, Jr, Molecular Recognition with Introverted Functionality Angewandte Chemie. ,vol. 39, pp. 3281- 3283 ,(2000) , 10.1002/1521-3773(20000915)39:18<3281::AID-ANIE3281>3.0.CO;2-P
J. Rebek, L. Marshall, J. McManis, R. Wolak, Convergent functional groups. 2. Structure and selectivity in olefin epoxidation with peracids Journal of Organic Chemistry. ,vol. 51, pp. 1649- 1653 ,(1986) , 10.1021/JO00360A003
Julius Rebek, Molecular Recognition with Model Systems Angewandte Chemie. ,vol. 29, pp. 245- 255 ,(1990) , 10.1002/ANIE.199002451
Tae Kyo Park, Joseph Schroeder, Julius Rebek, New molecular complements to imides. Complexation of thymine derivatives Journal of the American Chemical Society. ,vol. 113, pp. 5125- 5127 ,(1991) , 10.1021/JA00013A093
Julius. Rebek, David. Feitler, An improved method for the study of reaction intermediates. The mechanism of peptide synthesis mediated by carbodiimides. Journal of the American Chemical Society. ,vol. 95, pp. 4052- 4053 ,(1973) , 10.1021/JA00793A039
Tetsuo Iwasawa, Enrique Mann, Julius Rebek, A Reversible Reaction Inside a Self-Assembled Capsule Journal of the American Chemical Society. ,vol. 128, pp. 9308- 9309 ,(2006) , 10.1021/JA062768A