Ring size effects of some 13C, 31P and 195Pt NMR parameters in the series {Ph2P(CH2)nPh2}Pt(CH3)2

作者: S. Hietkamp , D.J. Stufkens , K. Vrieze

DOI: 10.1016/S0022-328X(00)81461-8

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摘要: Abstract The 31P, 13C, and 195Pt NMR spectra of the compounds {Ph2P(CH2)nPPh2}Pt(CH2)2 were studied compared with acyclic analogue, cis-(Ph2PCH3)2Pt(CH3)2. Comparison structural data showed that irregularities in parameters can be explained on basis existence angle strain for four-membered but not five-membered rings.

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