Complex Ternary Transition-Metal Hydrides and Hydridometalates
作者： W. Bronger , G. Auffermann
DOI: 10.1016/J.BBR.2011.03.031
关键词:
摘要: Various preparation routes led to a large number of complex ternary transition-metal hydrides and hydridometalates containing d- f-elements, together with alkali, alkaline-earth, rare-earth metals. Here, the parameter pressure is crucial tool for selective synthesis: increasing reaction leads higher oxidation states transition element. The crystal structures show broad variety different formations, whereby valence metals are favored, alkali metal as counterion. Moreover, mobility hydrogen atoms causes numerous order–disorder transitions.
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