Measurement of monomer reactivity ratios in the copolymerization of styrene and diethyl fumarate photoinitiated by benzil

作者: Huda Y. Al-Haddad , W.I. Bengough

DOI: 10.1016/0014-3057(89)90153-5

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摘要: Abstract The copolymerization of styrene and diethyl fumarate (DEF) photoinitiated by benzil was studied at 25° 60°. Copolymer compositions were obtained using [ 14 C]DEF. Monomer reactivity ratios found to be 0.50 ± 0.02 zero 0.27 0.035 0.015 60°, both Fineman-Ross Kelen-Tudos equations.

参考文章(7)
W.I. Bengough, G.B. Park, R.A. Young, The free radical initiated polymerization of diethylfumarate European Polymer Journal. ,vol. 11, pp. 305- 308 ,(1975) , 10.1016/0014-3057(75)90039-7
Kazuyuki Horie, Itaru Mita, Hirotaro Kambe, Calorimetric investigation of polymerization reactions. II. Copolymerization of diethyl fumarate with styrene Journal of Polymer Science Part A-1: Polymer Chemistry. ,vol. 7, pp. 2561- 2573 ,(1969) , 10.1002/POL.1969.150070909
Morton Fineman, Sidney D. Ross, Linear method for determining monomer reactivity ratios in copolymerization Journal of Polymer Science. ,vol. 5, pp. 259- 262 ,(1950) , 10.1002/POL.1950.120050210
J.C. Bevington, M. Johnson, J.P. Sheen, Radical reactions involving esters of fumaric acid—I. Copolymerizations European Polymer Journal. ,vol. 7, pp. 1147- 1153 ,(1971) , 10.1016/0014-3057(71)90147-9
T. Kelen, F. TÜd[Otilde]s, Analysis of the Linear Methods for Determining Copolymerization Reactivity Ratios. I. A New Improved Linear Graphic Method Journal of Macromolecular Science: Part A - Chemistry. ,vol. 9, pp. 1- 27 ,(1975) , 10.1080/00222337508068644
Frank R. Mayo, Frederick M. Lewis, Copolymerization. I. A Basis for Comparing the Behavior of Monomers in Copolymerization; The Copolymerization of Styrene and Methyl Methacrylate Journal of the American Chemical Society. ,vol. 66, pp. 1594- 1601 ,(1944) , 10.1021/JA01237A052
Frederick M. Lewis, Cheves Walling, William Cummings, Emorene R. Briggs, Frank R. Mayo, Copolymerization. IV. Effects of Temperature and Solvents on Monomer Reactivity Ratios Journal of the American Chemical Society. ,vol. 70, pp. 1519- 1523 ,(1948) , 10.1021/JA01184A066