Copper(II) ions capturing from water using ligand modified a new type mesoporous adsorbent

作者: Md. Rabiul Awual , Tsuyoshi Yaita , Sherif A. El-Safty , Hideaki Shiwaku , Shinichi Suzuki

DOI: 10.1016/J.CEJ.2013.02.016

关键词:

摘要: Abstract Highly selective mesoporous adsorbent design is necessary for detection and removal of toxic metals from drinking water with high efficiency cost-effective. The was fabricated by direct immobilization a synthesized (3-(3-(methoxycarbonyl)benzylidene) hydrazinyl)benzoic acid onto silica monoliths tested its potential application Cu(II) ions sensing wastewater. Specific nitrogen donor atoms containing novel ligand transformed the ion-sensing systems optically remove stable assemblies complexation mechanism. bonding to enhanced color formation capturing corresponding [Cu(II)-ligand] n + complexes. variation pH, contact time, limit initial concentration parameters were measured in sorption experiments. data revealed that new type able capacity extreme selectivity ionic competition. Therefore, offered simple procedure such low-level without using sophisticated instruments. effective pH range neutral region maximum as 145.98 mg/g. exhibited good recyclability several cycles use after operation deterioration significant performances. can be used effectively sensitive efficient wastewater treatment.

参考文章(46)
Peter Hoffmann, Speciation of iron John Wiley & Sons, Ltd. pp. 200- 217 ,(2005) , 10.1002/0470856009.CH2I(I)
Jafar Khosravi, Abdolmohammad Alamdari, Copper removal from oil-field brine by coprecipitation. Journal of Hazardous Materials. ,vol. 166, pp. 695- 700 ,(2009) , 10.1016/J.JHAZMAT.2008.11.079
Prasun K. Chatterjee, Arup K. SenGupta, Interference-free detection of trace copper in the presence of EDTA and other metals using two complementary chelating polymers Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 384, pp. 432- 441 ,(2011) , 10.1016/J.COLSURFA.2011.04.031
Hong Zhao, Ying Jiang, Yurong Ma, Zhijiao Wu, Qian Cao, Yujian He, Xiangjun Li, Zhuobin Yuan, Poly(2-amino-4-thiazoleacetic acid)/multiwalled carbon nanotubes modified glassy carbon electrodes for the electrochemical detection of copper(II) Electrochimica Acta. ,vol. 55, pp. 2518- 2521 ,(2010) , 10.1016/J.ELECTACTA.2009.12.008
J. Perić, M. Trgo, N. Vukojević Medvidović, Removal of zinc, copper and lead by natural zeolite-a comparison of adsorption isotherms. Water Research. ,vol. 38, pp. 1893- 1899 ,(2004) , 10.1016/J.WATRES.2003.12.035
Kavita G. Mester, David S. Kosson, Anaerobic biodegradation of toluene under denitrifying conditions in contaminated groundwater and soil Journal of Hazardous Materials. ,vol. 45, pp. 219- 232 ,(1996) , 10.1016/0304-3894(95)00095-X
Kaijun Wang, Baoshan Xing, Adsorption and desorption of cadmium by goethite pretreated with phosphate. Chemosphere. ,vol. 48, pp. 665- 670 ,(2002) , 10.1016/S0045-6535(02)00167-4
S. Larous, A.-H. Meniai, M. Bencheikh Lehocine, Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust Desalination. ,vol. 185, pp. 483- 490 ,(2005) , 10.1016/J.DESAL.2005.03.090
D. W. O'Connell, C. Birkinshaw, T. F. O'Dwyer, A chelating cellulose adsorbent for the removal of Cu(II) from aqueous solutions Journal of Applied Polymer Science. ,vol. 99, pp. 2888- 2897 ,(2006) , 10.1002/APP.22568