The oxidation of iron-chromium-manganese alloys at 900C

作者: A. L. Marasco , D. J. Young

DOI: 10.1007/BF00938460

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摘要: The oxidation of nine ternary iron-chromium-manganese alloys was studied at 900°C in an oxygen partial pressure 26.7 kPa. manganese concentration set 2, 6, and 10 wt. %, chromium 5, 12, 20 %. scales formed on the low-chromium consisted (Mn,Fe)2O3, α-Fe2O3, Fe3O4. These all exhibited internal scale detachment upon cooling. higher-chromium were complicated by nodule formation. Initially, these had outer layer MnCr2O4 with Cr2O3 underneath, adjacent to alloy. With passage time, however, nodules formed, overall reaction rate increased. This tendency more marked higher contents. Although contained a high content, product chromia usually manganese. It concluded that presence iron-chromium adverse effect resistance over wide range levels.

参考文章(15)
B. E. Hopkins, O. Kubaschewski, Oxidation of metals and alloys ,(1953)
D. L. Douglass, F. Gesmundo, C. de Asmundis, The air oxidation of an austenitic Fe-Mn-Cr stainless steel for fusion-reactor applications Oxidation of Metals. ,vol. 25, pp. 235- 268 ,(1986) , 10.1007/BF00655899
D. Mortimer, W. B. A. Sharp, Oxidation of Fe—Cr Binary Alloys British Corrosion Journal. ,vol. 3, pp. 61- 67 ,(1968) , 10.1179/000705968798326424
D. L. Douglass, J. S. Armijo, The influence of manganese and silicon on the oxidation behavior of Co-20Cr Oxidation of Metals. ,vol. 3, pp. 185- 202 ,(1971) , 10.1007/BF00603486
D. L. Douglass, J. S. Armijo, The Effect of Silicon and Manganese on the Oxidation Mechanism of Ni-20 Cr* Oxidation of Metals. ,vol. 2, pp. 207- 231 ,(1970) , 10.1007/BF00603657
G. N. Irving, J. Stringer, D. P. Whittle, Effect of the Possible fcc Stabilizers Mn, Fe, and Ni on the High-Temperature Oxidation of Co-Cr Alloys Oxidation of Metals. ,vol. 8, pp. 393- 407 ,(1974) , 10.1007/BF00603389
Jenq‐Gong Duh, Jyh‐Wei Lee, Diffusion‐Related Kinetics in the Oxidation‐Induced Phase Transformation of Fe‐9Al‐3Cr‐31Mn Alloys Journal of The Electrochemical Society. ,vol. 136, pp. 847- 853 ,(1989) , 10.1149/1.2096755
P. R. S. Jackson, G. R. Wallwork, The oxidation of binary iron-manganese alloys Oxidation of Metals. ,vol. 20, pp. 1- 17 ,(1983) , 10.1007/BF00658124
G.C. Wood, D.P. Whittle, The mechanism of breakthrough of protective chromium oxide scales on Fe-Cr alloys Corrosion Science. ,vol. 7, pp. 763- 782 ,(1967) , 10.1016/S0010-938X(67)80003-9