Electrospinning preparation and photoluminescence properties of erbium complex doped composite fibers

作者: Xiao Cui , He Ming Zhang , Tie Feng Wu

DOI: 10.1016/J.SAA.2011.05.107

关键词:

摘要: Abstract In this paper, an Er(III) complex of Er(DBM)3IPD, where DBM = 1,3-diphenyl-propane-1,3-dione and IPD = 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)-N,N-diphenylaniline, is synthesized doped into poly(vinylpyrrolidone) submicron fibers through electrospinning technique. The crystal structure morphology are investigated in detail. composite exhibit smooth uniform on the substrate, with average diameter ∼1.4 μm. Photophysical data suggest that DBM ligand sensitizes center efficiently provides optimal condition for radiative decay, low temperature can enhance emission intensity by suppressing quenching effect. It found photostability largely improved compared pure complex.

参考文章(23)
L‐N Sun, H‐J Zhang, L‐S Fu, F‐Y Liu, Q‐G Meng, C‐Y Peng, J‐B Yu, None, A New Sol–Gel Material Doped with an Erbium Complex and Its Potential Optical‐Amplification Application Advanced Functional Materials. ,vol. 15, pp. 1041- 1048 ,(2005) , 10.1002/ADFM.200400386
Daming Zhang, Cong Chen, Xu Sun, YuGuo Zhang, XiZhen Zhang, Aihua Wu, Bin Li, Daming Zhang, Optical properties of Er(DBM)3Phen-doped polymer and fabrication of ridge waveguide Optics Communications. ,vol. 278, pp. 90- 93 ,(2007) , 10.1016/J.OPTCOM.2007.06.015
Alpa C Patel, Shuxi Li, Ce Wang, Wanjin Zhang, Yen Wei, None, Electrospinning of Porous Silica Nanofibers Containing Silver Nanoparticles for Catalytic Applications Chemistry of Materials. ,vol. 19, pp. 1231- 1238 ,(2007) , 10.1021/CM061331Z
Liming Zhang, Bin Li, A series of Eu(III) emitters with a novel triphenylamine-derived beta-diketone ligand Journal of Luminescence. ,vol. 129, pp. 1304- 1308 ,(2009) , 10.1016/J.JLUMIN.2009.06.015
S. Moynihan, R. Van Deun, K. Binnemans, G. Redmond, Optical properties of planar polymer waveguides doped with organo-lanthanide complexes Optical Materials. ,vol. 29, pp. 1821- 1830 ,(2007) , 10.1016/J.OPTMAT.2006.10.005
Jamil A. Matthews, Gary E. Wnek, David G. Simpson, Gary L. Bowlin, Electrospinning of collagen nanofibers. Biomacromolecules. ,vol. 3, pp. 232- 238 ,(2002) , 10.1021/BM015533U
J. Barbillat, P. Le Barny, L. Divay, E. Lallier, A. Grisard, R. Van Deun, P. Fias, Near-infrared Fourier transform room-temperature photoluminescence of erbium complexes Review of Scientific Instruments. ,vol. 74, pp. 4954- 4957 ,(2003) , 10.1063/1.1614873
Q. Wang, N. K. Dutta, R. Ahrens, Spectroscopic properties of Er doped silica glasses Journal of Applied Physics. ,vol. 95, pp. 4025- 4028 ,(2004) , 10.1063/1.1669056
G. A. Kumar, Richard E. Riman, L. A. Diaz Torres, O. Barbosa Garcia, Santanu Banerjee, Anna Kornienko, John G. Brennan, Chalcogenide-Bound Erbium Complexes: Paradigm Molecules for Infrared Fluorescence Emission Chemistry of Materials. ,vol. 17, pp. 5130- 5135 ,(2005) , 10.1021/CM050770F