Simulation of transient state in enzymatic membrane reactors for resolution of DL-valine and experimental validation

作者: Antonio Bódalo , José L Gómez , Elisa Gómez , M Fuensanta Máximo , Asunción M Hidalgo

DOI: 10.1002/JCTB.480

关键词:

摘要: A simple model, based on kinetic studies, is shown to be capable of describing the transient state an ultrafiltration membrane reactor (UFMR) for continuous resolution DL-valine. The has been modelled as a perfectly mixed tank reactor. model validated in different conditions (five flow rates and three feeding concentrations) using asymmetrical hydrolysis N-acetyl-DL-valine catalysed by L-aminoacylase experimental system, with overall mean error 4.08%. © 2001 Society Chemical Industry

参考文章(19)
M. Satory, M. Fürlinger, D. Haltrich, K.D. Kulbe, F. Pittner, B. Nidetzky, Continuous enzymatic production of lactobionic acid using glucose-fructose oxidoreductase in an ultrafiltration membrane reactor Biotechnology Letters. ,vol. 19, pp. 1205- 1208 ,(1997) , 10.1023/A:1018485804167
Colin Flock, Amarjeet Bassi, Mark Gijzen, Removal of aqueous phenol and 2-chlorophenol with purified soybean peroxidase and raw soybean hulls Journal of Chemical Technology & Biotechnology. ,vol. 74, pp. 303- 309 ,(1999) , 10.1002/(SICI)1097-4660(199904)74:4<303::AID-JCTB38>3.0.CO;2-B
Lucyna Slomińska, Włodzimierz Grajek, Anna Grześkowiak, Maria Gocalek, Enzymatic starch saccharification in an ultrafiltration membrane reactor Starch-starke. ,vol. 50, pp. 390- 396 ,(1998) , 10.1002/(SICI)1521-379X(199809)50:9<390::AID-STAR390>3.0.CO;2-W
Yasuyuki Isono, Mitsutoshi Nakajima, Hiroshi Nabetani, Solvent-Free Esterification of Oleic Acid and Oleyl Alcohol Using Membrane Reactor and Lipase-Surfactant Complex Journal of Fermentation and Bioengineering. ,vol. 86, pp. 138- 140 ,(1998) , 10.1016/S0922-338X(98)80048-2
Piero Pasta, Giacomo Carrea, Enrico Monzani, Nicoletta Gaggero, Stefano Colonna, Chloroperoxidase-catalyzed enantioselective oxidation of methyl phenyl sulfide with dihydroxyfumaric acid/oxygen or ascorbic acid/oxygen as oxidants Biotechnology and Bioengineering. ,vol. 62, pp. 489- 493 ,(1999) , 10.1002/(SICI)1097-0290(19990220)62:4<489::AID-BIT13>3.0.CO;2-7
W.F. Blatt, B.G. Hudson, S.M. Robinson, E.M. Zipilivan, A modified ultrafiltration cell for separating the products of proteolysis Analytical Biochemistry. ,vol. 22, pp. 161- 165 ,(1968) , 10.1016/0003-2697(68)90270-4
Mitsutoshi Nakajima, Tamotsu Shoji, Hiroshi Nabetani, Protease hydrolysis of water soluble fish proteins using a free enzyme membrane reactor Process Biochemistry. ,vol. 27, pp. 155- 160 ,(1992) , 10.1016/0032-9592(92)87003-Y
C. Wandrey, CONTINUOUS HOMOGENEOUS CATALYSIS IN ENZYME ENGINEERING Annals of the New York Academy of Sciences. ,vol. 326, pp. 87- 95 ,(1979) , 10.1111/J.1749-6632.1979.TB14153.X
A Bódalo, J.L Gómez, E Gómez, J Bastida, G León, M.F Máximo, A.M Hidalgo and, M.C Montiel, Kinetic calculations in the enzymatic resolution of DL-amino acids Enzyme and Microbial Technology. ,vol. 24, pp. 381- 387 ,(1999) , 10.1016/S0141-0229(98)00136-7