Acidity and concentrations of ionic species of PM2.5 in Hong Kong

作者: Ravi Kant Pathak , Xiaohong Yao , Alexis KH Lau , Chak K Chan , None

DOI: 10.1016/S1352-2310(02)00958-5

关键词:

摘要: Abstract The strong acidity and the concentrations of ammonium, sodium, sulfate, nitrate chloride in PM2.5 Hong Kong were measured using a Harvard honeycomb denuder/filter-pack system. role atmospheric mixing height variation species was investigated contribution long-range transport to ambient aerosols quantitatively determined. average spring, summer, autumn winter 2000, spring 2001 49(23–92), 27(11–52), 97(71–145), 45(26–57), 103(78–167) nmol/m3, respectively. Simulations aerosol inorganic model (AIM2) revealed that situ only minor fraction (23–39%) because presence bisulfate ions. correlated with large difference between relative humidity estimated deliquescence aerosols. In equivalent concentrations, acidity, ammonium sulfate accounted for 16% (9–21%), 31% (26–39%) 42% (40–45%) water-soluble species, Analysis air mass trajectories showed through East/South China Sea (marine) mainland (continental) possible. When under influence marine masses, correlation height. Continental found increase by 49–383% 33–302%, total, about 40% this study from continental masses. However, masses on concentration not obvious.

参考文章(27)
Xiaohong Yao, Ming Fang, Chak K. Chan, Experimental study of the sampling artifact of chloride depletion from collected sea salt aerosols. Environmental Science & Technology. ,vol. 35, pp. 600- 605 ,(2001) , 10.1021/ES000964Q
Takaaki Shimohara, Okihiro Oishi, Akira Utsunomiya, Hitoshi Mukai, Shiro Hatakeyama, Jang Eun-Suk, Itsushi Uno, Kentaro Murano, Characterization of atmospheric air pollutants at two sites in northern Kyushu, Japan - Chemical form, and chemical reaction Atmospheric Environment. ,vol. 35, pp. 667- 681 ,(2001) , 10.1016/S1352-2310(00)00340-X
Thomas McCurdy, Michael P. Zelenka, Philip M. Lawrence, Robert M. Houston, Robert Burton, Acid aerosols in the Pittsburgh Metropolitan area Atmospheric Environment. ,vol. 33, pp. 5133- 5145 ,(1999) , 10.1016/S1352-2310(99)00119-3
Y. Qin, Chak K. Chan, L.Y. Chan, Characteristics of chemical compositions of atmospheric aerosols in Hong Kong: spatial and seasonal distributions Science of The Total Environment. ,vol. 206, pp. 25- 37 ,(1997) , 10.1016/S0048-9697(97)00214-3
Hong Zhuang, Chak K Chan, Ming Fang, Anthony S Wexler, Formation of nitrate and non-sea-salt sulfate on coarse particles Atmospheric Environment. ,vol. 33, pp. 4223- 4233 ,(1999) , 10.1016/S1352-2310(99)00186-7
Chul H. Song, Gregory R. Carmichael, The aging process of naturally emitted aerosol (sea-salt and mineral aerosol) during long range transport Atmospheric Environment. ,vol. 33, pp. 2203- 2218 ,(1999) , 10.1016/S1352-2310(98)00301-X
Hong Zhuang, Chak K Chan, Ming Fang, Anthony S Wexler, Size distributions of particulate sulfate, nitrate, and ammonium at a coastal site in Hong Kong Atmospheric Environment. ,vol. 33, pp. 843- 853 ,(1999) , 10.1016/S1352-2310(98)00305-7
Hak Sung Lee, Richard A. Wadden, Peter A. Scheff, Measurement and evaluation of acid air pollutants in Chicago using an annular denuder system Atmospheric Environment. Part A. General Topics. ,vol. 27, pp. 543- 553 ,(1993) , 10.1016/0960-1686(93)90211-G
Gerald J. Keeler, John D. Spengler, Raymond A. Castillo, Acid aerosol measurements at a suburban Connecticut site Atmospheric Environment. Part A. General Topics. ,vol. 25, pp. 681- 690 ,(1991) , 10.1016/0960-1686(91)90066-G
Petros Koutrakis, Jack M. Wolfson, John D. Spengler, An improved method for measuring aerosol strong acidity: Results from a nine-month study in St Louis, Missouri and Kingston, Tennessee Atmospheric Environment. ,vol. 22, pp. 157- 162 ,(1988) , 10.1016/0004-6981(88)90308-3