Living polymerization of α-olefins with an α-diimine Ni(II) catalyst : Formation of well-defined ethylene-propylene copolymers through controlled chain-walking
作者： Jeffrey M. Rose , Anna E. Cherian , Geoffrey W. Coates
DOI: 10.1021/JA058183I
关键词:
摘要: A C2-symmetric Ni(II) catalyst was found to polymerize α-olefins with high levels of ω,2-regiochemistry. The resulting products are ethylene−propylene-type copolymers methylene sequences precise length between methyl branches. Modification reaction conditions can introduce ω,1-enchainments into the polymers which increases average
acs.org
unirioja.es
sci-hub.se 参考文章(0)