One-step hydrothermal method for preparation of Ni/carbon thin film electrodes for efficient electroreduction of imidacloprid

作者: Liping Huang , Xiaohui Zhou , Xiao Liu , Zongyu Liu , Ying Tian

DOI: 10.1039/D0NJ05509C

关键词:

摘要: Carbon thin film (CTF)-modified electrodes were successfully prepared on Ni substrates via a one-step hydrothermal method. The properties of the films investigated by X-ray diffraction patterns, scanning electron microscopy and Fourier transform infrared spectroscopy. Specific surface area porosity calculated from N2 adsorption desorption isotherms. Electroactivity was assessed electrochemical impedance CTF at 180 °C showed coarse morphology with large number carbon spheres (Φ1–4 μm) 76.77 m2 g−1 good electroactivity low charge transfer resistance. CTF-modified substrate used as an electrode for electroreduction imidacloprid, achieving 92.1% removal efficiency imidacloprid.

参考文章(34)
Maria-Magdalena Titirici, Markus Antonietti, Niki Baccile, Hydrothermal carbon from biomass : a comparison of the local structure from poly- to monosaccharides and pentoses/hexoses. Green Chemistry. ,vol. 10, pp. 1204- 1212 ,(2008) , 10.1039/B807009A
Cristina Segura, Claudio Zaror, Héctor D. Mansilla, María Angélica Mondaca, Imidacloprid oxidation by photo-Fenton reaction. Journal of Hazardous Materials. ,vol. 150, pp. 679- 686 ,(2008) , 10.1016/J.JHAZMAT.2007.05.018
Shanyu Zhao, Daniel C. Cooper, Haixun Xu, Pinghua Zhu, J. William Suggs, Synthesis of a sugar-organometallic compound 1,1′-difurfurylferrocene and its microwave preparation of carbon/iron oxide nanocomposite Applied Surface Science. ,vol. 264, pp. 242- 246 ,(2013) , 10.1016/J.APSUSC.2012.10.008
M. Ferreira, M.F. Pinto, I.C. Neves, A.M. Fonseca, O.S.G.P. Soares, J.J.M. Órfão, M.F.R. Pereira, J.L. Figueiredo, P. Parpot, Electrochemical oxidation of aniline at mono and bimetallic electrocatalysts supported on carbon nanotubes Chemical Engineering Journal. ,vol. 260, pp. 309- 315 ,(2015) , 10.1016/J.CEJ.2014.08.005
Marc Bourgin, Frédéric Violleau, Laurent Debrauwer, Joël Albet, Ozonation of imidacloprid in aqueous solutions: reaction monitoring and identification of degradation products. Journal of Hazardous Materials. ,vol. 190, pp. 60- 68 ,(2011) , 10.1016/J.JHAZMAT.2011.02.065
S. Malato, J. Caceres, A. Agüera, M. Mezcua, D. Hernando, J. Vial, A. R. Fernández-Alba, Degradation of imidacloprid in water by photo-Fenton and TiO2 photocatalysis at a solar pilot plant: a comparative study. Environmental Science & Technology. ,vol. 35, pp. 4359- 4366 ,(2001) , 10.1021/ES000289K
Zhijun Luo, Sheng Yin, Kun Wang, Huaming Li, Leigang Wang, Hui Xu, Jiexiang Xia, Synthesis of one-dimensional β-Ni(OH)2 nanostructure and their application as nonenzymatic glucose sensors Materials Chemistry and Physics. ,vol. 132, pp. 387- 394 ,(2012) , 10.1016/J.MATCHEMPHYS.2011.11.041
Hongxia Luo, Zujin Shi, Nanqiang Li, Zhennan Gu, Qiankun Zhuang, Investigation of the Electrochemical and Electrocatalytic Behavior of Single-Wall Carbon Nanotube Film on a Glassy Carbon Electrode Analytical Chemistry. ,vol. 73, pp. 915- 920 ,(2001) , 10.1021/AC000967L
Meral Turabik, Nihal Oturan, Belgin Gözmen, Mehmet A. Oturan, Efficient removal of insecticide "imidacloprid" from water by electrochemical advanced oxidation processes. Environmental Science and Pollution Research. ,vol. 21, pp. 8387- 8397 ,(2014) , 10.1007/S11356-014-2788-9
Guohua Zhao, Xiao Cui, Meichuan Liu, Peiqiang Li, Yonggang Zhang, Tongcheng Cao, Hongxu Li, Yanzhu Lei, Lei Liu, Dongming Li, Electrochemical degradation of refractory pollutant using a novel microstructured TiO2 nanotubes/ Sb-doped SnO2 electrode. Environmental Science & Technology. ,vol. 43, pp. 1480- 1486 ,(2009) , 10.1021/ES802155P