Synthesis of an amphiphilic metalloporphyrin and a novel gas sensor fabricated with Langmuir-Blodgett films

作者: Yunqi Liu , Qu Liang , Yu Xu , Fushen Chen , Daoben Zhu

DOI: 10.1016/0038-1098(96)00230-X

关键词:

摘要: Abstract An amphiphilic metalloporphyrin, cobalt (II) 5, 10, 15-tri( p -octadecyloxyphenyl)-20-( -hydroxyphenyl)porphyrin (CoPPC 18 ) was synthesized and characterized. The molecules of CoPPC alone form moderate stable monolayer at the air-water interface a clear phase transition observed in surface pressure-area isotherm. optical Mach-Zhender interferometer prepared as novel sensor element incorporating with Langmuir-Blodgett films. preliminary result indicates that is sensitive reversible on exposure to NO 2 gas room temperature.

参考文章(4)
Raymond Bonnett, Stella Ioannou, Andrew G. James, Christopher W. Pitt, Moe M. Z. Soe, Octadecyl ethers of 5,10,15,20-tetra(4-hydroxyphenyl)porphyrin: synthesis and film-forming properties Journal of Materials Chemistry. ,vol. 2, pp. 823- 828 ,(1992) , 10.1039/JM9920200823
S.-R. Kim, S.-A. Choi, J.-D. Kim, K.H. Choi, S.K. Park, Y.H. Chang, The characteristics of metallophthalocyanine mono-, multilayer and application to the gas sensor for NO2 Synthetic Metals. ,vol. 71, pp. 2293- 2294 ,(1995) , 10.1016/0379-6779(94)03264-7
N. Inagaki, S. Tasaka, Y. Ikeda, Plasma polymerization of copper phthalocyanines and application of the plasma polymer films to NO2 gas sensor device Journal of Applied Polymer Science. ,vol. 55, pp. 1451- 1464 ,(1995) , 10.1002/APP.1995.070551010