ScCO2 assisted preparation of supported metal NPs. Application to catalyst design.
作者： Oana Pascu , Bastien Cacciuttolo , Samuel Marre , Mathieu Pucheault , Cyril Aymonier
DOI: 10.1016/J.SUPFLU.2014.11.013
关键词:
摘要: Designing and developing materials with specific properties are nowadays important tasks. These could be achieved by choosing the adequate conditions, from a myriad of possibilities, being aware that slight changes in preparation method have major impact on final material. With work presented here, we showing kinetically controlled surface nano-structuring (NPs formation deposition over solid supports) scCO2 is versatile way for preparing active materials. Size, composition, morphology organization/architecture supported metal NPs can playing type metal, precursor, reaction media composition (stronger or weaker reducing media) different supports employed. Moreover, direct correlation between physical (size, morphology, organization) chemical (composition, chemistry) demonstrated systems catalytic behaviour, yield selectivity, exemplified N-alkylation amines alcohols.
archives-ouvertes.fr
elsevier.com
sci-hub.se 参考文章(29)
D. Sanli, S. E. Bozbag, C. Erkey, Synthesis of nanostructured materials using supercritical CO2: Part I. Physical transformations Journal of Materials Science. ,vol. 47, pp. 2995- 3025 ,(2012) , 10.1007/S10853-011-6054-Y
Mélanie Majimel, Samuel Marre, Elsa Garrido, Cyril Aymonier, Supercritical Fluid Chemical Deposition as an Alternative Process to CVD for the Surface Modification of Materials Chemical Vapor Deposition. ,vol. 17, pp. 342- 352 ,(2011) , 10.1002/CVDE.201106921
Clive H. Yen, Kenichi Shimizu, Ying-Ying Lin, Franklin Bailey, I. Francis Cheng, Chien M. Wai, Chemical Fluid Deposition of Pt-Based Bimetallic Nanoparticles on Multiwalled Carbon Nanotubes for Direct Methanol Fuel Cell Application Energy & Fuels. ,vol. 21, pp. 2268- 2271 ,(2007) , 10.1021/EF0606409
Cyril Aymonier, Anne Loppinet-Serani, Helen Reverón, Yves Garrabos, François Cansell, Review of supercritical fluids in inorganic materials science Journal of Supercritical Fluids. ,vol. 38, pp. 242- 251 ,(2006) , 10.1016/J.SUPFLU.2006.03.019
Can Erkey, Preparation of metallic supported nanoparticles and films using supercritical fluid deposition The Journal of Supercritical Fluids. ,vol. 47, pp. 517- 522 ,(2009) , 10.1016/J.SUPFLU.2008.10.019
Samuel Couillaud, Marina Kirikova, Warda Zaïdi, Jean-Pierre Bonnet, Samuel Marre, Cyril Aymonier, Junxian Zhang, Fermin Cuevas, Michel Latroche, Luc Aymard, Jean-Louis Bobet, Supercritical fluid chemical deposition of Pd nanoparticles on magnesium–scandium alloy for hydrogen storage Journal of Alloys and Compounds. ,vol. 574, pp. 6- 12 ,(2013) , 10.1016/J.JALLCOM.2013.03.229
François Cansell, Cyril Aymonier, Design of functional nanostructured materials using supercritical fluids The Journal of Supercritical Fluids. ,vol. 47, pp. 508- 516 ,(2009) , 10.1016/J.SUPFLU.2008.10.002
M.J. Tenorio, C. Pando, J.A.R. Renuncio, J.G. Stevens, R.A. Bourne, M. Poliakoff, A. Cabañas, Adsorption of Pd(hfac)2 on mesoporous silica SBA-15 using supercritical CO2 and its role in the performance of Pd–SiO2 catalyst The Journal of Supercritical Fluids. ,vol. 69, pp. 21- 28 ,(2012) , 10.1016/J.SUPFLU.2012.05.003
Samuel Marre, Arnaud Erriguible, Arturo Perdomo, Francois Cansell, Frederic Marias, Cyril Aymonier, Kinetically Controlled Formation of Supported Nanoparticles in Low Temperature Supercritical Media for the Development of Advanced Nanostructured Materials Journal of Physical Chemistry C. ,vol. 113, pp. 5096- 5104 ,(2009) , 10.1021/JP809533N
Feng Shi, Man Kin Tse, Shaolin Zhou, Marga-Martina Pohl, Jörg Radnik, Sandra Hübner, Klaus Jähnisch, Angelika Brückner, Matthias Beller, Green and Efficient Synthesis of Sulfonamides Catalyzed by Nano-Ru/Fe3O4 Journal of the American Chemical Society. ,vol. 131, pp. 1775- 1779 ,(2009) , 10.1021/JA807681V