A generalized mixing rule for hard-sphere equations of state of Percus–Yevick type

作者: Mohammad K. Khoshkbarchi , Juan H. Vera

DOI: 10.1016/S0378-3812(97)00230-6

关键词:

摘要: Abstract An analogical approach has been used to extend mixtures the radial distribution function of Percus–Yevick type equations state for hard spheres. The proposed follows same formalism employed by Mansoori et al. Carnahan–Starling equation state. generality method permits with different singularities. In this work, it is applied an which meets correct low density and high limits, previously Khoshkbarchi Vera. results show that both resulting a mixture spheres, developed in study, can accurately represent computer simulation data while satisfying limit at close-packing.

参考文章(17)
Boris Barboy, William M. Gelbart, Series representation of the equation of state for hard particle fluids Journal of Chemical Physics. ,vol. 71, pp. 3053- 3062 ,(1979) , 10.1063/1.438711
Tomáš Boublík, Ivo Nezbeda, P-V-T behaviour of hard body fluids. Theory and experiment Collection of Czechoslovak Chemical Communications. ,vol. 51, pp. 2301- 2432 ,(1986) , 10.1135/CCCC19862301
Tomáš Boublík, Hard‐Sphere Equation of State The Journal of Chemical Physics. ,vol. 53, pp. 471- 472 ,(1970) , 10.1063/1.1673824
G. Jackson, J. S. Rowlinson, F. Van Swol, Computer simulation of mixtures of hard spheres The Journal of Physical Chemistry. ,vol. 91, pp. 4907- 4912 ,(1987) , 10.1021/J100303A007
J. L. Lebowitz, J. S. Rowlinson, Thermodynamic Properties of Mixtures of Hard Spheres Journal of Chemical Physics. ,vol. 41, pp. 133- 138 ,(1964) , 10.1063/1.1725611
Mohammad K Khoshkbarchi, Juan H Vera, A simplified hard-sphere equation of state meeting the high and low density limits Fluid Phase Equilibria. ,vol. 130, pp. 189- 194 ,(1997) , 10.1016/S0378-3812(96)03189-5
M. S. Wertheim, Analytic Solution of the Percus‐Yevick Equation Journal of Mathematical Physics. ,vol. 5, pp. 643- 651 ,(1964) , 10.1063/1.1704158
B. J. Alder, Studies in Molecular Dynamics. III. A Mixture of Hard Spheres The Journal of Chemical Physics. ,vol. 40, pp. 2724- 2730 ,(1964) , 10.1063/1.1725587