作者: Juan Jin , Ming-Jun Jia , Yu Peng , Jie-Hui Yu , Ji-Qing Xu
DOI: 10.1039/C1CE05038A
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摘要: The room-temperature incorporation of the additional inorganic anionic groups SCN− and SO42− into CdX2-piperazine (pip) system in acidic H2O/C2H5OH solutions generated first example a piperazinium-templated 1-D tube-like cadmium–bromothiocyanato sulfate [H2pip]4[Cd3Br8(SCN)2(SO4)2(H2O)]·4H2O 1 isostructural ribboned cadmium–halothiocyanato coordination polymers [CdX(SCN)L] [X− = Br−2, I−3; L SC(OC2H5)NH2] with ancillary organic S-donor ligand L. was derived from situ nucleophilic addition reaction between SCN−group C2H5OH solvent.