I-V characteristics of single and clustered ligand stabilized cobalt nanoparticles on highly oriented pyrolytic graphite obtained with conducting atomic force microscopy under ambient conditions

作者: J. Fetting , N. Mill , A. Hütten , G. Reiss , M. K.-H. Peter

DOI: 10.1063/1.4766754

关键词:

摘要: Cobalt nanoparticles are of large interest for applications in magnetic devices and healthcare. We studied their properties by conducting atomic force microscopy on clusters particles single deposited highly oriented pyrolytic graphite. Topography conductance maps have been taken simultaneously I-V curves were measured at predefined locations nanoparticle nanoparticles. The corresponded to an energy band gap the density states 3.7 eV which matches CoO nanostructures while a particle showed only 1.3 eV is similar indirect Co3O4. Moreover, we found resistive switching, i.e., change clusters’ resistance during sweeping voltage. As reason, suggest transition from Co3O4 due heating effects.

参考文章(20)
Yonatan Dubi, Massimiliano Di Ventra, Colloquium: Heat flow and thermoelectricity in atomic and molecular junctions Reviews of Modern Physics. ,vol. 83, pp. 131- 155 ,(2011) , 10.1103/REVMODPHYS.83.131
A. V. Mugtasimov, N. V. Peskov, G. V. Pankina, P. A. Chernavskii, V. V. Lunin, The kinetics of low-temperature oxidation of cobalt nanoparticles in porous media Russian Journal of Physical Chemistry A. ,vol. 85, pp. 217- 224 ,(2011) , 10.1134/S0036024411020257
Shouheng Sun, Christopher B Murray, Dieter Weller, Liesl Folks, Andreas Moser, Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices Science. ,vol. 287, pp. 1989- 1992 ,(2000) , 10.1126/SCIENCE.287.5460.1989
Alexander Weddemann, Inga Ennen, Anna Regtmeier, Camelia Albon, Annalena Wolff, Katrin Eckstädt, Nadine Mill, Michael K-H Peter, Jochen Mattay, Carolin Plattner, Norbert Sewald, Andreas Hütten, Review and outlook: from single nanoparticles to self-assembled monolayers and granular GMR sensors Beilstein Journal of Nanotechnology. ,vol. 1, pp. 75- 93 ,(2010) , 10.3762/BJNANO.1.10
Victor F Puntes, Kannan M Krishnan, A Paul Alivisatos, Colloidal Nanocrystal Shape and Size Control: The Case of Cobalt Science. ,vol. 291, pp. 2115- 2117 ,(2001) , 10.1126/SCIENCE.1057553
Lei Fu, ZHIMIN Liu, Yunqi Liu, Buxing Han, Pingan Hu, Lingchao Cao, DAOBEN Zhu, Beaded Cobalt Oxide Nanoparticles along Carbon Nanotubes: Towards More Highly Integrated Electronic Devices Advanced Materials. ,vol. 17, pp. 217- 221 ,(2005) , 10.1002/ADMA.200400833
Earl A. Gulbransen, Kenneth F. Andrew, The Kinetics of the Oxidation of Cobalt Journal of The Electrochemical Society. ,vol. 98, pp. 241- 251 ,(1951) , 10.1149/1.2778139
H. G. Tompkins, J. A. Augis, Summary Abstract: Oxidation of cobalt in air from room temperature to 467 °C Journal of Vacuum Science and Technology. ,vol. 18, pp. 408- 409 ,(1981) , 10.1116/1.570799