Chiral crystals based on achiral ligand and their framework dependent luminescent properties

作者: Zhiyong Hu , Qiong Zhang , Mingzhu Zhang , Wei Du , Yaqin Wang

DOI: 10.1016/J.INOCHE.2018.09.016

关键词:

摘要: Abstract Two novel chiral crystals were prepared by utilizing the spatial distortions of achiral ligands under same coordination environment. We find that in environment, as radius halogen atoms decreases, number hydrogen bonds which turn affects distortion and leads to chirality. Experiments showed they have good photophysical properties stability, was further proved theoretical calculations. Additionally, bioimaging performed extend their application biological development.

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