Study of the biodegradation levels of oils from the Orinoco Oil Belt (Junin area) using different biodegradation scales

作者: Liliana López

DOI: 10.1016/J.ORGGEOCHEM.2013.10.014

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摘要: Abstract This work presents a study of the molecular composition saturated and aromatic hydrocarbon fractions crude oils from Orinoco Oil Belt (Junin area) in Eastern Venezuelan Basin, with purpose classifying these samples following two distinct biodegradation assessment schemes: PM scale [Peters, K.E., Moldowan, J.M., 1993. The Biomarker Guide: Interpreting Molecular Fossils Petroleum Ancient Sediments. Prentice Hall, Englewood Cliffs, New Jersey, p. 363] Manco [Larter, S., Huang, H., Adams, J., Bennett, B., Snowdon, L.R., 2012. A practical for use reservoir geochemical studies biodegraded oils. Organic Geochemistry 45, 66–76]. Both scales agree on presence different levels analyzed oils, although they are based groups compounds. uses mainly compounds (e.g., n -alkanes, acyclic isoprenoids, terpanes steranes) as well steroids. On other hand, considers alkyltoluenes, naphthalene, methylnaphthalene, phenanthrene, alkylphenanthrenes methyldibenzothiophenes) not included scale. Thus, combined allows determination level both compound classes. Dibenzothiophene (DBT), which was score determination, also shows variations peak intensity when compared to C 4 -alkylnaphthalenes, presumably associated process biological alteration. differences observed present may be attributed parameters that control rates laterally across area or existence varying communities microorganisms, among possible factors.

参考文章(33)
K. E. Peters, C. C. Walters, J. M. Moldowan, The Biomarker Guide bigu. pp. 490- ,(2004) , 10.1017/CBO9780511524868
F. Cassani, G. Eglinton, Organic geochemistry of Venezuelan extra-heavy oils Chemical Geology. ,vol. 56, pp. 167- 183 ,(1986) , 10.1016/0009-2541(86)90001-X
Dietrich H. Welte, Bernard P. Tissot, Petroleum Formation and Occurrence ,(1989)
John Meacham Hunt, Petroleum Geochemistry and Geology ,(1995)
M. L. Chirinos, I. Layrisse, N. de Audemard, Physical and Chemical Characterization of Heavy Crude Oil in the Orinoco Oil Belt: Section II. Characterization, Maturation, and Degradation AAPG Special Volumes. ,vol. 81, pp. 183- 191 ,(1987)
John K. Volkman, Robert Alexander, Robert Ian Kagi, Garry Wayne Woodhouse, Demethylated hopanes in crude oils and their applications in petroleum geochemistry Geochimica et Cosmochimica Acta. ,vol. 47, pp. 785- 794 ,(1983) , 10.1016/0016-7037(83)90112-6
Jie Lu, Toshiaki Nakajima-Kambe, Toshiya Shigeno, Akiko Ohbo, Nobuhiko Nomura, Tadaatsu Nakahara, Biodegradation of dibenzothiophene and 4,6-dimethyldibenzothiophene by Sphingomonas paucimobilis strain TZS-7. Journal of Bioscience and Bioengineering. ,vol. 88, pp. 293- 299 ,(1999) , 10.1016/S1389-1723(00)80012-2
Stefania Frassinetti, Leonardo Setti, Andrea Corti, Paolo Farrinelli, Piercarlo Montevecchi, Giovanni Vallini, Biodegradation of dibenzothiophene by a nodulating isolate of Rhizobium meliloti. Canadian Journal of Microbiology. ,vol. 44, pp. 289- 297 ,(1998) , 10.1139/W97-155